Zemmelink Hendrik J.

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Zemmelink
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Hendrik J.
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  • Article
    CO2 deposition over the multi-year ice of the western Weddell Sea
    (American Geophysical Union, 2006-07-13) Zemmelink, Hendrik J. ; Delille, Bruno ; Tison, Jean-Louis ; Hintsa, Eric J. ; Houghton, Leah A. ; Dacey, John W. H.
    Field measurements by eddy correlation (EC) indicate an average uptake of 0.6 g CO2 m−2 d−1 by the ice-covered western Weddell Sea in December 2004. At the same time, snow that covers ice floes of the western Weddell Sea becomes undersaturated with CO2 relative to the atmosphere during early summer. Gradients of CO2 from the ice to the atmosphere do not support significant diffusive fluxes and are not strong enough to explain the observed CO2 deposition. We hypothesize that the transport of air through the snow pack is controlled by turbulence and that undersaturation of CO2 is caused by biological productivity at the ice-snow and snow-atmosphere interface. The total carbon uptake by the multi-year ice zone of the western Weddell Sea in December could have been as high as 6.6 Tg C y−1.
  • Article
    Relaxed eddy accumulation measurements of the sea-to-air transfer of dimethylsulfide over the northeastern Pacific
    (American Geophysical Union, 2004-01-30) Zemmelink, Hendrik J. ; Gieskes, Winfried W. C. ; Klaassen, Wim ; Beukema, Wim J. ; de Groot, Henk W. ; Baar, Hein J. W. de ; Hintsa, Eric J. ; McGillis, Wade R. ; Dacey, John W. H.
    Gas transfer rates were determined from relaxed eddy accumulation (REA) measurements of the flux of dimethylsulfide (DMS) over the northeastern Pacific Ocean. This first application of the REA technique for the measurement of DMS fluxes over the open ocean produced estimates of the gas transfer rate that are on average higher than those calculated from commonly used parameterizations. The relationship between the total gas transfer rate and wind speed was found to be gas kgas = 0.53 (±0.05) U102. Because of the effect of the airside resistance, the waterside transfer rate was up to 16% higher than kgas. Removal of the airside transfer component from the total transfer rate resulted in a relation between wind speed and waterside transfer of k660 = 0.61 (±0.06) U102. However, DMS fluxes showed a high degree of scatter that could not readily be accounted for by wind speed and atmospheric stability. It has to be concluded that these measurements do not permit an accurate parameterization of gas transfer as a function of wind speed.
  • Article
    Sea-to-air fluxes from measurements of the atmospheric gradient of dimethylsulfide and comparison with simultaneous relaxed eddy accumulation measurements
    (American Geophysical Union, 2004-01-30) Hintsa, Eric J. ; Dacey, John W. H. ; McGillis, Wade R. ; Edson, James B. ; Zappa, Christopher J. ; Zemmelink, Hendrik J.
    We measured vertical profiles of dimethylsulfide (DMS) in the atmospheric marine boundary layer from R/P FLIP during the 2000 FAIRS cruise. Applying Monin-Obukhov similarity theory to the DMS gradients and simultaneous micrometeorological data, we calculated sea-to-air DMS fluxes for 34 profiles. From the fluxes and measured seawater DMS concentrations, we calculated the waterside gas transfer velocity, kw. Gas transfer velocities from the gradient flux approach are within the range of previous commonly used parameterizations of kw as a function of wind speed but are a factor of 2 smaller than simultaneous determinations of transfer velocity using the relaxed eddy accumulation technique. This is the first field comparison of these different techniques for measuring DMS flux from the ocean; the accuracy of the techniques and possible reasons for the discrepancy are discussed.
  • Article
    Direct measurements of biogenic dimethylsulphide fluxes from the oceans : a synthesis
    (National Research Council Canada, 2004-06-24) Zemmelink, Hendrik J. ; Dacey, John W. H. ; Hintsa, Eric J.
    This paper provides a brief overview of the state-of-the-art of techniques that are currently used for field measurements of trace gas fluxes and the subsequent derivation of gas transfer rates over the oceans. Special attention is given to the relaxed eddy accumulation (REA) and gradient flux (GF) techniques, which rely on empirical functions thus far mainly validated over land. The universality of these functions and their application at sea have not yet been fully evaluated. New experiments have shown that the emission of dimethylsulphide (DMS) can be measured by the REA and GF techniques. Moreover, these measurements have provided parameterizations of gas exchange rates that are within the range of relationships between wind speed and gas transfer that have recently been derived from eddy correlation (EC) and deliberate tracer measurements. Using DMS as a model, gas is potentially a powerful approach to intercalibrate the REA, GF, and EC techniques, test their applicability in the marine environment, and investigate processes that determine trace gas exchange across the ocean surface.
  • Article
    Supplement to physical exchanges at the air–sea interface : UK–SOLAS field measurements
    (American Meteorological Society, 2009-05) Brooks, Ian M. ; Yelland, Margaret J. ; Upstill-Goddard, Robert C. ; Nightingale, Philip D. ; Archer, Stephen D. ; D'Asaro, Eric A. ; Beale, Rachael ; Beatty, Cory ; Blomquist, Byron ; Bloom, A. Anthony ; Brooks, Barbara J. ; Cluderay, John ; Coles, David ; Dacey, John W. H. ; DeGrandpre, Michael D. ; Dixon, Jo ; Drennan, William M. ; Gabriele, Joseph ; Goldson, Laura E. ; Hardman-Mountford, Nick ; Hill, Martin K. ; Horn, Matt ; Hsueh, Ping-Chang ; Huebert, Barry ; De Leeuw, Gerrit ; Leighton, Timothy G. ; Liddicoat, Malcolm ; Lingard, Justin J. N. ; McNeil, Craig L. ; McQuaid, James B. ; Moat, Bengamin I. ; Moore, Gerald ; Neill, Craig L. ; Norris, Sarah J. ; O'Doherty, Simon ; Pascal, Robin W. ; Prytherch, John ; Rebozo, Mike ; Sahlee, Erik ; Salter, Matt ; Schuster, Ute ; Skjelvan, Ingunn ; Slagter, Hans ; Smith, Michael H. ; Smith, Paul D. ; Srokosz, Meric ; Stephens, John A. ; Taylor, Peter K. ; Telszewski, Maciej ; Walsh, Roisin ; Ward, Brian ; Woolf, David K. ; Young, Dickon ; Zemmelink, Hendrik J.
  • Article
    Dimethylsulfide emissions over the multi-year ice of the western Weddell Sea
    (American Geophysical Union, 2008-03-20) Zemmelink, Hendrik J. ; Dacey, John W. H. ; Houghton, Leah A. ; Hintsa, Eric J. ; Liss, P. S.
    This study, conducted in December 2004, is the first to present observations of DMS in a snow pack covering the multi-year sea ice of the western Weddell Sea. The snow layer is important because it is the interface through which DMS needs to be transported in order to be emitted directly from the ice to the overlying atmosphere. High concentrations of DMS, up to 6000 nmol m−3, were found during the first weeks of December but concentrations sharply decline as late spring-early summer progresses. This implies that DMS contained in sea ice is efficiently vented through the snow into the atmosphere. Indeed, field measurements by relaxed eddy accumulation indicate an average release of 11 μmol DMS m−2 d−1 from the ice and snow throughout December.
  • Article
    Fluxes and gas transfer rates of the biogenic trace gas DMS derived from atmospheric gradients
    (American Geophysical Union, 2004-06-30) Zemmelink, Hendrik J. ; Dacey, John W. H. ; Hintsa, Eric J. ; McGillis, Wade R. ; Gieskes, Winfried W. C. ; Klaassen, Wim ; de Groot, Henk W. ; Baar, Hein J. W. de
    Gas transfer rates were determined from vertical profile measurements of atmospheric dimethylsulfide (DMS) gradients over the equatorial Pacific Ocean obtained during the GasEx-2001 cruise. A quadratic relationship between gas transfer velocity and wind speed was derived from the DMS flux measurements; this relationship was in close agreement with a parameterization derived from relaxed eddy accumulation measurements of DMS over the northeastern Pacific Ocean. However, the GasEx-2001 relationship results in gas transfer rates that are a factor 2 higher than gas transfer rates calculated from a parameterization that is based on coincident eddy correlation measurements of CO2 flux. The measurement precision of both the profiling and eddy correlation techniques applied during GasEx-2001 is comparable; the two gas transfer data sets are in agreement within their uncertainty. Differences in the number of samples and the wind speed range over which CO2 and DMS fluxes were measured are likely causes for the observed discrepancy.
  • Article
    Environmental turbulent mixing controls on air-water gas exchange in marine and aquatic systems
    (American Geophysical Union, 2007-05-17) Zappa, Christopher J. ; McGillis, Wade R. ; Raymond, Peter A. ; Edson, James B. ; Hintsa, Eric J. ; Zemmelink, Hendrik J. ; Dacey, John W. H. ; Ho, David T.
    Air-water gas transfer influences CO2 and other climatically important trace gas fluxes on regional and global scales, yet the magnitude of the transfer is not well known. Widely used models of gas exchange rates are based on empirical relationships linked to wind speed, even though physical processes other than wind are known to play important roles. Here the first field investigations are described supporting a new mechanistic model based on surface water turbulence that predicts gas exchange for a range of aquatic and marine processes. Findings indicate that the gas transfer rate varies linearly with the turbulent dissipation rate to the inline equation power in a range of systems with different types of forcing - in the coastal ocean, in a macro-tidal river estuary, in a large tidal freshwater river, and in a model (i.e., artificial) ocean. These results have important implications for understanding carbon cycling.
  • Article
    Emission of dimethylsulfide from Weddell Sea leads
    (American Geophysical Union, 2005-12-10) Zemmelink, Hendrik J. ; Houghton, Leah A. ; Dacey, John W. H. ; Worby, A. P. ; Liss, P. S.
    The distribution of dimethylsulfide (DMS), dimethylsulfoniopropionate (DMSP) and dimethylsulfoxide (DMSO) was examined in lead water in pack ice of the Weddell Sea. Samples were taken by pulling water into a syringe from a series of depths from 0.002 m to 4 m and deeper. Concentrations of DMS, DMSP and DMSO remained low throughout the water column relative to surface water, which was highly enriched. Concentrations of the major sulfur compounds increased by over an order of magnitude during periods with smooth surface water conditions. This increase coincided with a profound stratification of the water column, caused by a decrease in salinity of near surface water. We estimate that the DMS emission from leads and open water in Antarctic sea ice could contribute significantly to the yearly DMS flux from the Southern Ocean.
  • Article
    Physical exchanges at the air–sea interface : UK–SOLAS field measurements
    (American Meteorological Society, 2009-05) Brooks, Ian M. ; Bloom, A. Anthony ; Brooks, Barbara J. ; Lingard, Justin J. N. ; McQuaid, James B. ; Norris, Sarah J. ; Smith, Michael H. ; Smith, Paul D. ; Yelland, Margaret J. ; Moat, Bengamin I. ; Pascal, Robin W. ; Prytherch, John ; Srokosz, Meric ; Taylor, Peter K. ; Upstill-Goddard, Robert C. ; Salter, Matt ; Nightingale, Philip D. ; Archer, Stephen D. ; Beale, Rachael ; Dixon, Jo ; Goldson, Laura E. ; Hardman-Mountford, Nick ; Liddicoat, Malcolm ; Moore, Gerald ; Stephens, John A. ; D'Asaro, Eric A. ; McNeil, Craig L. ; Beatty, Cory ; DeGrandpre, Michael D. ; Blomquist, Byron ; Huebert, Barry ; Cluderay, John ; Zemmelink, Hendrik J. ; Coles, David ; Hsueh, Ping-Chang ; Leighton, Timothy G. ; Dacey, John W. H. ; Drennan, William M. ; Rebozo, Mike ; Sahlee, Erik ; Gabriele, Joseph ; Hill, Martin K. ; Horn, Matt ; De Leeuw, Gerrit ; Neill, Craig ; Skjelvan, Ingunn ; O'Doherty, Simon ; Walsh, Roisin ; Young, Dickon ; Schuster, Ute ; Telszewski, Maciej ; Slagter, Hans ; Ward, Brian ; Woolf, David K.
    As part of the U.K. contribution to the international Surface Ocean–Lower Atmosphere Study, a series of three related projects—DOGEE, SEASAW, and HiWASE—undertook experimental studies of the processes controlling the physical exchange of gases and sea spray aerosol at the sea surface. The studies share a common goal: to reduce the high degree of uncertainty in current parameterization schemes. The wide variety of measurements made during the studies, which incorporated tracer and surfactant release experiments, included direct eddy correlation fluxes, detailed wave spectra, wind history, photographic retrievals of whitecap fraction, aerosol-size spectra and composition, surfactant concentration, and bubble populations in the ocean mixed layer. Measurements were made during three cruises in the northeast Atlantic on the RRS Discovery during 2006 and 2007; a fourth campaign has been making continuous measurements on the Norwegian weather ship Polarfront since September 2006. This paper provides an overview of the three projects and some of the highlights of the measurement campaigns.
  • Article
    Gradients in dimethylsulfide, dimethylsulfoniopropionate, dimethylsulfoxide, and bacteria near the sea surface
    (Inter-Research, 2005-06-23) Zemmelink, Hendrik J. ; Houghton, Leah A. ; Sievert, Stefan M. ; Frew, Nelson M. ; Dacey, John W. H.
    Gradients of dimethylsulfide (DMS), dimethylsulfoniopropionate (DMSP), dimethylsulfoxide (DMSO), and bacterial numbers and diversity from the surface microlayer to 500 cm depth were assessed in coastal waters surrounding the Martha’s Vineyard Coastal Observatory, Massachusetts, USA. Microlayer samples were collected with a surface skimmer: a partially submerged, rotating glass cylinder (‘drum’) that allows the collection of a thin layer of water by adherence to the drum. A depletion of DMS towards the water surface (10 cm) was found at all sampling days, with largest gradients during rough sea surface conditions. The steep gradients show that gas fluxes and transfer velocities, based on the concentration disequilibrium between the water and the atmosphere, need to be based on near surface gas concentration values. Elevated DMSP, DMSO concentrations and bacterial numbers were found at the sea surface during calm conditions. Although degassing and photo-oxidation on the skimmer will bias the microlayer data, the results indicate stratification of DMSP, DMSO and bacteria during periods of smooth sea surface conditions.