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Using present-day observations to detect when anthropogenic change forces surface ocean carbonate chemistry outside preindustrial bounds

(Copernicus Publications on behalf of the European Geosciences Union, 2016-09-13) Sutton, Adrienne J. ; Sabine, Chris L. ; Feely, Richard A. ; Cai, Wei-Jun ; Cronin, Meghan F. ; McPhaden, Michael J. ; Morell, Julio M. ; Newton, Jan A. ; Noh, Jae Hoon ; Ólafsdóttir, Sólveig R. ; Salisbury, Joseph E. ; Send, Uwe ; Vandemark, Douglas ; Weller, Robert A.

One of the major challenges to assessing the impact of ocean acidification on marine life is detecting and interpreting long-term change in the context of natural variability. This study addresses this need through a global synthesis of monthly pH and aragonite saturation state (Ωarag) climatologies for 12 open ocean, coastal, and coral reef locations using 3-hourly moored observations of surface seawater partial pressure of CO2 and pH collected together since as early as 2010. Mooring observations suggest open ocean subtropical and subarctic sites experience present-day surface pH and Ωarag conditions outside the bounds of preindustrial variability throughout most, if not all, of the year. In general, coastal mooring sites experience more natural variability and thus, more overlap with preindustrial conditions; however, present-day Ωarag conditions surpass biologically relevant thresholds associated with ocean acidification impacts on Mytilus californianus (Ωarag < 1.8) and Crassostrea gigas (Ωarag < 2.0) larvae in the California Current Ecosystem (CCE) and Mya arenaria larvae in the Gulf of Maine (Ωarag < 1.6). At the most variable mooring locations in coastal systems of the CCE, subseasonal conditions approached Ωarag =  1. Global and regional models and data syntheses of ship-based observations tended to underestimate seasonal variability compared to mooring observations. Efforts such as this to characterize all patterns of pH and Ωarag variability and change at key locations are fundamental to assessing present-day biological impacts of ocean acidification, further improving experimental design to interrogate organism response under real-world conditions, and improving predictive models and vulnerability assessments seeking to quantify the broader impacts of ocean acidification.
Seasonal variation of ocean bottom pressure derived from Gravity Recovery and Climate Experiment (GRACE) : local validation and global patterns

(American Geophysical Union, 2005-09-02) Kanzow, Torsten ; Flechtner, Frank ; Chave, Alan D. ; Schmidt, Roland ; Schwintzer, Peter ; Send, Uwe

The Gravity Recovery and Climate Experiment (GRACE) processing centers at the GeoForschungsZentrum Potsdam (GFZ) and the University of Texas Center for Space Research (UTCSR) provide time series of monthly gravity field solutions covering the period since mission launch in March 2002. Although the achieved accuracy still remains an order of magnitude below the mission's baseline goal, these time series have successfully been used to study terrestrial phenomena such as water storage variations. Over the oceans, the monthly gravity field solutions can be converted into estimates of the fluctuating ocean bottom pressure (OBP), which is the sum of atmospheric and oceanic mass variations. The GRACE products may be validated against in situ OBP observations which are available from a ground truth site in the tropical northwest Atlantic Ocean. Large differences are observed between the in situ and GRACE-derived OBP which are investigated by comparing the tidal and nontidal ocean models used at GFZ and UTCSR for dealiasing short-term (<2 months) mass variations from satellite measurements. Results show that the barotropic nontidal and tide models need improvement at periods shorter than 1 day and longer than 2 weeks. On a global scale the monthly OBP fields from GRACE generally overestimate the variability compared to ocean general circulation models, especially in tropical regions. This may be attributed to continuing deficiencies in GRACE data processing. Nevertheless, there is some initial evidence that GRACE possesses the potential to observe large-scale averages of bottom pressure fluctuations.
On the development of SWOT in situ calibration/validation for short-wavelength ocean topography

(American Meteorological Society, 2022-05-01) Wang, Jinbo ; Fu, Lee-Lueng ; Haines, Bruce ; Lankhorst, Matthias ; Lucas, Andrew J. ; Farrar, J. Thomas ; Send, Uwe ; Meinig, Christian ; Schofield, Oscar M. E. ; Ray, Richard D.

The future Surface Water and Ocean Topography (SWOT) mission aims to map sea surface height (SSH) in wide swaths with an unprecedented spatial resolution and subcentimeter accuracy. The instrument performance needs to be verified using independent measurements in a process known as calibration and validation (Cal/Val). The SWOT Cal/Val needs in situ measurements that can make synoptic observations of SSH field over an O(100) km distance with an accuracy matching the SWOT requirements specified in terms of the along-track wavenumber spectrum of SSH error. No existing in situ observing system has been demonstrated to meet this challenge. A field campaign was conducted during September 2019–January 2020 to assess the potential of various instruments and platforms to meet the SWOT Cal/Val requirement. These instruments include two GPS buoys, two bottom pressure recorders (BPR), three moorings with fixed conductivity–temperature–depth (CTD) and CTD profilers, and a glider. The observations demonstrated that 1) the SSH (hydrostatic) equation can be closed with 1–3 cm RMS residual using BPR, CTD mooring and GPS SSH, and 2) using the upper-ocean steric height derived from CTD moorings enable subcentimeter accuracy in the California Current region during the 2019/20 winter. Given that the three moorings are separated at 10–20–30 km distance, the observations provide valuable information about the small-scale SSH variability associated with the ocean circulation at frequencies ranging from hourly to monthly in the region. The combined analysis sheds light on the design of the SWOT mission postlaunch Cal/Val field campaign.
CODE-2 : moored array and large-scale data report

(Woods Hole Oceanographic Institution, 1985-11) Alessi, Carol A. ; Beardsley, Robert C. ; Limeburner, Richard ; Rosenfeld, Leslie K. ; Lentz, Steven J. ; Send, Uwe ; Winant, Clinton D. ; Allen, John S. ; Halliwell, George R. ; Brown, Wendell S. ; lrish, James D.

The Coastal Ocean Dynamics Experiment (CODE) was undertaken to identify and study the important dynamical processes which govern the wind-driven motion of coastal water over the continental shelf. The initial effort in this multi-year, multi-institutional research program was to obtain high-quality data sets of all the relevant physical variables needed to construct accurate kinematic and dynamic descriptions of the response of shelf water to strong wind forcing in the 2 to 10 day band. A series of two small-scale, densely- instrumented field experiments of approximately four months duration (called CODE-1 and CODE-2) were designed to explore and to determine the kinematics and momentum and heat balances of the local wind-driven flow over a region of the northern California shelf which is characterized by both relatively simple bottom topography and large wind stress events in both winter and summer. A more lightly instrumented, long -term, large-scale component was designed to help separate the local wind-driven response in the region of the small-scale experiments from motions generated either offshore by the California Current system or in some distant region along the coast, and also to help determine the seasonal cycles of the atmospheric forcing, water structure, and coastal currents over the northern California shelf. The first small-scale experiment (CODE-1) was conducted between April and August, 1981 as a pilot study in "which primary emphasis was placed on characterizing the wind-driven "signal" and the "noise" from which this signal must be extracted. In particular, CODE-1 was designed to identify the key features of the circulation and its variability over the northern California shelf and to determine the important time and length scales of the wind-driven response. The second small-scale experiment (CODE-2) was conducted between April and August, 1982 and was designed to sample more carefully the mesoscale horizonta1 variability observed in CODE-1. This report presents a basic description of the moored array data and some other Eulerian data collected during CODE-2. A brief description of the CODE-2 field program is presented first, followed by a description of the common data analysis procedures used to produce the various data sets presented here. Then basic descriptions of the following data sets are presented: (a) the coastal and moored meteorological measurements, (b) the moored current measurements, (c) array plots of the surface wind stress and near-surface current measurements, (d) the moored temperature and conductivity observations, (e) the bottom pressure measurements, and (f) the wind and adjusted coastal sea level observations obtained as part of the CODE-2 large-scale component.
The mid-depth circulation of the northwestern tropical Atlantic observed by floats

( 2009-05-29) Lankhorst, Matthias ; Fratantoni, David M. ; Ollitrault, Michel ; Richardson, Philip L. ; Send, Uwe ; Zenk, Walter

A comprehensive analysis of velocity data from subsurface floats in the northwestern tropical Atlantic at two depth layers is presented: one representing the Antarctic Intermediate Water (AAIW, pressure range 600–1050 dbar), the other the upper North Atlantic Deep Water (uNADW, pressure range 1200–2050 dbar). New data from three independent research programs are combined with previously available data to achieve blanket coverage in space for the AAIW layer, while coverage in the uNADW remains more intermittent. Results from the AAIW mainly confirm previous studies on the mean flow, namely the equatorial zonal and the boundary currents, but clarify details on pathways, mostly by virtue of the spatial data coverage that sets float observations apart from e. g. shipborne or mooring observations. Mean transports in each of five zonal equatorial current bands is found to be between 2.7 and 4.5 Sv. Pathways carrying AAIW northward beyond the North Brazil Undercurrent are clearly visible in the mean velocity field, in particular a northward transport of 3.7 Sv across 16° N between the Antilles islands and the Mid- Atlantic Ridge. New maps of Lagrangian eddy kinetic energy and integral time scales are presented to quantify mesoscale activity. For the uNADW, mean flow and mesoscale properties are discussed as data availability allows. Trajectories in the uNADWeast of the Lesser Antilles reveal interactions between the Deep Western Boundary Current (DWBC) and the basin interior, which can explain recent hydrographic observations of changes in composition of DWBC water along its southward flow.
ASIRI : an ocean–atmosphere initiative for Bay of Bengal

(American Meteorological Society, 2016-11-22) Wijesekera, Hemantha W. ; Shroyer, Emily L. ; Tandon, Amit ; Ravichandran, M. ; Sengupta, Debasis ; Jinadasa, S. U. P. ; Fernando, Harindra J. S. ; Agrawal, Neeraj ; Arulananthan, India K. ; Bhat, G. S. ; Baumgartner, Mark F. ; Buckley, Jared ; Centurioni, Luca R. ; Conry, Patrick ; Farrar, J. Thomas ; Gordon, Arnold L. ; Hormann, Verena ; Jarosz, Ewa ; Jensen, Tommy G. ; Johnston, T. M. Shaun ; Lankhorst, Matthias ; Lee, Craig M. ; Leo, Laura S. ; Lozovatsky, Iossif ; Lucas, Andrew J. ; MacKinnon, Jennifer A. ; Mahadevan, Amala ; Nash, Jonathan D. ; Omand, Melissa M. ; Pham, Hieu ; Pinkel, Robert ; Rainville, Luc ; Ramachandran, Sanjiv ; Rudnick, Daniel L. ; Sarkar, Sutanu ; Send, Uwe ; Sharma, Rashmi ; Simmons, Harper L. ; Stafford, Kathleen M. ; St. Laurent, Louis C. ; Venayagamoorthy, Subhas K. ; Venkatesan, Ramasamy ; Teague, William J. ; Wang, David W. ; Waterhouse, Amy F. ; Weller, Robert A. ; Whalen, Caitlin B.

Air–Sea Interactions in the Northern Indian Ocean (ASIRI) is an international research effort (2013–17) aimed at understanding and quantifying coupled atmosphere–ocean dynamics of the Bay of Bengal (BoB) with relevance to Indian Ocean monsoons. Working collaboratively, more than 20 research institutions are acquiring field observations coupled with operational and high-resolution models to address scientific issues that have stymied the monsoon predictability. ASIRI combines new and mature observational technologies to resolve submesoscale to regional-scale currents and hydrophysical fields. These data reveal BoB’s sharp frontal features, submesoscale variability, low-salinity lenses and filaments, and shallow mixed layers, with relatively weak turbulent mixing. Observed physical features include energetic high-frequency internal waves in the southern BoB, energetic mesoscale and submesoscale features including an intrathermocline eddy in the central BoB, and a high-resolution view of the exchange along the periphery of Sri Lanka, which includes the 100-km-wide East India Coastal Current (EICC) carrying low-salinity water out of the BoB and an adjacent, broad northward flow (∼300 km wide) that carries high-salinity water into BoB during the northeast monsoon. Atmospheric boundary layer (ABL) observations during the decaying phase of the Madden–Julian oscillation (MJO) permit the study of multiscale atmospheric processes associated with non-MJO phenomena and their impacts on the marine boundary layer. Underway analyses that integrate observations and numerical simulations shed light on how air–sea interactions control the ABL and upper-ocean processes.
Satellite detection of dinoflagellate blooms off California by UV reflectance ratios

(University of California Press, 2021-06-09) Kahru, Mati ; Anderson, Clarissa ; Barton, Andrew D. ; Carter, Melissa L. ; Catlett, Dylan ; Send, Uwe ; Sosik, Heidi M. ; Weiss, Elliot L. ; Mitchell, B. Gregory

As harmful algae blooms are increasing in frequency and magnitude, one goal of a new generation of higher spectral resolution satellite missions is to improve the potential of satellite optical data to monitor these events. A satellite-based algorithm proposed over two decades ago was used for the first time to monitor the extent and temporal evolution of a massive bloom of the dinoflagellate Lingulodinium polyedra off Southern California during April and May 2020. The algorithm uses ultraviolet (UV) data that have only recently become available from the single ocean color sensor on the Japanese GCOM-C satellite. Dinoflagellates contain high concentrations of mycosporine-like amino acids and release colored dissolved organic matter, both of which absorb strongly in the UV part of the spectrum. Ratios <1 of remote sensing reflectance of the UV band at 380 nm to that of the blue band at 443 nm were used as an indicator of the dinoflagellate bloom. The satellite data indicated that an observed, long, and narrow nearshore band of elevated chlorophyll-a (Chl-a) concentrations, extending from northern Baja to Santa Monica Bay, was dominated by L. polyedra. In other high Chl-a regions, the ratios were >1, consistent with historical observations showing a sharp transition from dinoflagellate- to diatom-dominated waters in these areas. UV bands are thus potentially useful in the remote sensing of phytoplankton blooms but are currently available only from a single ocean color sensor. As several new satellites such as the NASA Plankton, Aerosol, Cloud, and marine Ecosystem mission will include UV bands, new algorithms using these bands are needed to enable better monitoring of blooms, especially potentially harmful algal blooms, across large spatiotemporal scales.
CALYPSO 2019 Cruise Report: field campaign in the Mediterranean

(Woods Hole Oceanographic Institution, 2020-01) Mahadevan, Amala ; D'Asaro, Eric A. ; Allen, John T. ; Almaraz García, Pablo ; Alou-Font, Eva ; Aravind, Harilal Meenambika ; Balaguer, Pau ; Caballero, Isabel ; Calafat, Noemi ; Carbornero, Andrea ; Casas, Benjamin ; Castilla, Carlos ; Centurioni, Luca R. ; Conley, Margaret ; Cristofano, Gino ; Cutolo, Eugenio ; Dever, Mathieu ; Enrique Navarro, Angélica ; Falcieri, Francesco ; Freilich, Mara ; Goodwin, Evan ; Graham, Raymond ; Guigand, Cedric ; Hodges, Benjamin A. ; Huntley, Helga ; Johnston, T. M. Shaun ; Lankhorst, Matthias ; Lermusiaux, Pierre F. J. ; Lizaran, Irene ; Mirabito, Chris ; Miralles, A. ; Mourre, Baptiste ; Navarro, Gabriel ; Ohmart, Michael ; Ouala, Said ; Ozgokmen, Tamay M. ; Pascual, Ananda ; Pou, Joan Mateu Horrach ; Poulain, Pierre Marie ; Ren, Alice ; Tarry, Daniel R. ; Rudnick, Daniel L. ; Rubio, M. ; Ruiz, Simon ; Rypina, Irina I. ; Tintore, Joaquin ; Send, Uwe ; Shcherbina, Andrey Y. ; Torner, Marc ; Salvador-Vieira, Guilherme ; Wirth, Nikolaus ; Zarokanellos, Nikolaos

This cruise aimed to identify transport pathways from the surface into the interior ocean during the late winter in the Alborán sea between the Strait of Gibraltar (5°40’W) and the prime meridian. Theory and previous observations indicated that these pathways likely originated at strong fronts, such as the one that separates salty Mediterranean water and the fresher water in owing from the Atlantic. Our goal was to map such pathways and quantify their transport. Since the outcropping isopycnals at the front extend to the deepest depths during the late winter, we planned the cruise at the end of the Spring, prior to the onset of thermal stratification of the surface mixed layer.
Atlantic meridional overturning circulation: Observed transport and variability

(Frontiers Media, 2019-06-07) Frajka-Williams, Eleanor ; Ansorge, Isabelle ; Baehr, Johanna ; Bryden, Harry L. ; Chidichimo, Maria Paz ; Cunningham, Stuart A. ; Danabasoglu, Gokhan ; Dong, Shenfu ; Donohue, Kathleen A. ; Elipot, Shane ; Heimbach, Patrick ; Holliday, Naomi Penny ; Hummels, Rebecca ; Jackson, Laura C. ; Karstensen, Johannes ; Lankhorst, Matthias ; Le Bras, Isabela A. ; Lozier, M. Susan ; McDonagh, Elaine L. ; Meinen, Christopher S. ; Mercier, Herlé ; Moat, Bengamin I. ; Perez, Renellys ; Piecuch, Christopher G. ; Rhein, Monika ; Srokosz, Meric ; Trenberth, Kevin E. ; Bacon, Sheldon ; Forget, Gael ; Goni, Gustavo J. ; Kieke, Dagmar ; Koelling, Jannes ; Lamont, Tarron ; McCarthy, Gerard D. ; Mertens, Christian ; Send, Uwe ; Smeed, David A. ; Speich, Sabrina ; van den Berg, Marcel ; Volkov, Denis L. ; Wilson, Christopher G.

The Atlantic Meridional Overturning Circulation (AMOC) extends from the Southern Ocean to the northern North Atlantic, transporting heat northwards throughout the South and North Atlantic, and sinking carbon and nutrients into the deep ocean. Climate models indicate that changes to the AMOC both herald and drive climate shifts. Intensive trans-basin AMOC observational systems have been put in place to continuously monitor meridional volume transport variability, and in some cases, heat, freshwater and carbon transport. These observational programs have been used to diagnose the magnitude and origins of transport variability, and to investigate impacts of variability on essential climate variables such as sea surface temperature, ocean heat content and coastal sea level. AMOC observing approaches vary between the different systems, ranging from trans-basin arrays (OSNAP, RAPID 26°N, 11°S, SAMBA 34.5°S) to arrays concentrating on western boundaries (e.g., RAPID WAVE, MOVE 16°N). In this paper, we outline the different approaches (aims, strengths and limitations) and summarize the key results to date. We also discuss alternate approaches for capturing AMOC variability including direct estimates (e.g., using sea level, bottom pressure, and hydrography from autonomous profiling floats), indirect estimates applying budgetary approaches, state estimates or ocean reanalyses, and proxies. Based on the existing observations and their results, and the potential of new observational and formal synthesis approaches, we make suggestions as to how to evaluate a comprehensive, future-proof observational network of the AMOC to deepen our understanding of the AMOC and its role in global climate.
Dinoflagellate vertical migration fuels an intense red tide

(National Academy of Sciences, 2023-08-28) Zheng, Bofu ; Lucas, Andrew J. ; Franks, Peter J. S. ; Schlosser, Tamara L. ; Anderson, Clarissa R. ; Send, Uwe ; Davis, Kristen ; Barton, Andrew D. ; Sosik, Heidi M.

Harmful algal blooms (HABs) are increasing globally, causing economic, human health, and ecosystem harm. In spite of the frequent occurrence of HABs, the mechanisms responsible for their exceptionally high biomass remain imperfectly understood. A 50-y-old hypothesis posits that some dense blooms derive from dinoflagellate motility: organisms swim upward during the day to photosynthesize and downward at night to access deep nutrients. This allows dinoflagellates to outgrow their nonmotile competitors. We tested this hypothesis with in situ data from an autonomous, ocean-wave-powered vertical profiling system. We showed that the dinoflagellate Lingulodinium polyedra’s vertical migration led to depletion of deep nitrate during a 2020 red tide HAB event. Downward migration began at dusk, with the maximum migration depth determined by local nitrate concentrations. Losses of nitrate at depth were balanced by proportional increases in phytoplankton chlorophyll concentrations and suspended particle load, conclusively linking vertical migration to the access and assimilation of deep nitrate in the ocean environment. Vertical migration during the red tide created anomalous biogeochemical conditions compared to 70 y of climatological data, demonstrating the capacity of these events to temporarily reshape the coastal ocean’s ecosystem and biogeochemistry. Advances in the understanding of the physiological, behavioral, and metabolic dynamics of HAB-forming organisms from cutting-edge observational techniques will improve our ability to forecast HABs and mitigate their consequences in the future.
Bay of Bengal intraseasonal oscillations and the 2018 monsoon onset

(American Meteorological Society, 2021-10-01) Shroyer, Emily L. ; Tandon, Amit ; Sengupta, Debasis ; Fernando, Harindra J. S. ; Lucas, Andrew J. ; Farrar, J. Thomas ; Chattopadhyay, Rajib ; de Szoeke, Simon P. ; Flatau, Maria ; Rydbeck, Adam ; Wijesekera, Hemantha W. ; McPhaden, Michael J. ; Seo, Hyodae ; Subramanian, Aneesh C. ; Venkatesan, Ramasamy ; Joseph, Jossia K. ; Ramsundaram, S. ; Gordon, Arnold L. ; Bohman, Shannon M. ; Pérez, Jaynise ; Simoes-Sousa, Iury T. ; Jayne, Steven R. ; Todd, Robert E. ; Bhat, G. S. ; Lankhorst, Matthias ; Schlosser, Tamara L. ; Adams, Katherine ; Jinadasa, S. U. P. ; Mathur, Manikandan ; Mohapatra, Mrutyunjay ; Pattabhi Rama Rao, Eluri ; Sahai, Atul Kumar ; Sharma, Rashmi ; Lee, Craig ; Rainville, Luc ; Cherian, Deepak A. ; Cullen, Kerstin ; Centurioni, Luca R. ; Hormann, Verena ; MacKinnon, Jennifer A. ; Send, Uwe ; Anutaliya, Arachaporn ; Waterhouse, Amy F. ; Black, Garrett S. ; Dehart, Jeremy A. ; Woods, Kaitlyn M. ; Creegan, Edward ; Levy, Gad ; Kantha, Lakshmi ; Subrahmanyam, Bulusu

In the Bay of Bengal, the warm, dry boreal spring concludes with the onset of the summer monsoon and accompanying southwesterly winds, heavy rains, and variable air–sea fluxes. Here, we summarize the 2018 monsoon onset using observations collected through the multinational Monsoon Intraseasonal Oscillations in the Bay of Bengal (MISO-BoB) program between the United States, India, and Sri Lanka. MISO-BoB aims to improve understanding of monsoon intraseasonal variability, and the 2018 field effort captured the coupled air–sea response during a transition from active-to-break conditions in the central BoB. The active phase of the ∼20-day research cruise was characterized by warm sea surface temperature (SST > 30°C), cold atmospheric outflows with intermittent heavy rainfall, and increasing winds (from 2 to 15 m s−1). Accumulated rainfall exceeded 200 mm with 90% of precipitation occurring during the first week. The following break period was both dry and clear, with persistent 10–12 m s−1 wind and evaporation of 0.2 mm h−1. The evolving environmental state included a deepening ocean mixed layer (from ∼20 to 50 m), cooling SST (by ∼1°C), and warming/drying of the lower to midtroposphere. Local atmospheric development was consistent with phasing of the large-scale intraseasonal oscillation. The upper ocean stores significant heat in the BoB, enough to maintain SST above 29°C despite cooling by surface fluxes and ocean mixing. Comparison with reanalysis indicates biases in air–sea fluxes, which may be related to overly cool prescribed SST. Resolution of such biases offers a path toward improved forecasting of transition periods in the monsoon.
Autonomous seawater pCO2 and pH time series from 40 surface buoys and the emergence of anthropogenic trends

(Copernicus Publications, 2019-03-26) Sutton, Adrienne J. ; Feely, Richard A. ; Maenner-Jones, Stacy ; Musielwicz, Sylvia ; Osborne, John ; Dietrich, Colin ; Monacci, Natalie ; Cross, Jessica N. ; Bott, Randy ; Kozyr, Alex ; Andersson, Andreas J. ; Bates, Nicholas R. ; Cai, Wei-Jun ; Cronin, Meghan F. ; De Carlo, Eric H. ; Hales, Burke ; Howden, Stephan D. ; Lee, Charity M. ; Manzello, Derek P. ; McPhaden, Michael J. ; Meléndez, Melissa ; Mickett, John B. ; Newton, Jan A. ; Noakes, Scott ; Noh, Jae Hoon ; Olafsdottir, Solveig R. ; Salisbury, Joseph E. ; Send, Uwe ; Trull, Thomas W. ; Vandemark, Douglas ; Weller, Robert A.

Ship-based time series, some now approaching over 3 decades long, are critical climate records that have dramatically improved our ability to characterize natural and anthropogenic drivers of ocean carbon dioxide (CO2) uptake and biogeochemical processes. Advancements in autonomous marine carbon sensors and technologies over the last 2 decades have led to the expansion of observations at fixed time series sites, thereby improving the capability of characterizing sub-seasonal variability in the ocean. Here, we present a data product of 40 individual autonomous moored surface ocean pCO2 (partial pressure of CO2) time series established between 2004 and 2013, 17 also include autonomous pH measurements. These time series characterize a wide range of surface ocean carbonate conditions in different oceanic (17 sites), coastal (13 sites), and coral reef (10 sites) regimes. A time of trend emergence (ToE) methodology applied to the time series that exhibit well-constrained daily to interannual variability and an estimate of decadal variability indicates that the length of sustained observations necessary to detect statistically significant anthropogenic trends varies by marine environment. The ToE estimates for seawater pCO2 and pH range from 8 to 15 years at the open ocean sites, 16 to 41 years at the coastal sites, and 9 to 22 years at the coral reef sites. Only two open ocean pCO2 time series, Woods Hole Oceanographic Institution Hawaii Ocean Time-series Station (WHOTS) in the subtropical North Pacific and Stratus in the South Pacific gyre, have been deployed longer than the estimated trend detection time and, for these, deseasoned monthly means show estimated anthropogenic trends of 1.9±0.3 and 1.6±0.3 µatm yr−1, respectively. In the future, it is possible that updates to this product will allow for the estimation of anthropogenic trends at more sites; however, the product currently provides a valuable tool in an accessible format for evaluating climatology and natural variability of surface ocean carbonate chemistry in a variety of regions. Data are available at https://doi.org/10.7289/V5DB8043 and https://www.nodc.noaa.gov/ocads/oceans/Moorings/ndp097.html (Sutton et al., 2018).

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