McIntosh William C.

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McIntosh
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William C.
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  • Preprint
    The origin of HIMU in the SW Pacific : evidence from intraplate volcanism in southern New Zealand and subantarctic islands
    ( 2006-02-17) Panter, Kurt S. ; Blusztajn, Jerzy S. ; Hart, Stanley R. ; Kyle, K. R. ; Esser, R. ; McIntosh, William C.
    This paper presents field, geochemical and isotopic (Sr, Nd, Pb) results on basalts from the Antipodes, Campbell and Chatham Islands, New Zealand. New 40Ar/39Ar age determinations along with previous K-Ar dates reveal three major episodes of volcanic activity on Chatham Island (85-82, 41-35, ~5 Ma). Chatham and Antipodes samples comprise basanite, alkali and transitional basalts that have HIMU-like isotopic (206Pb/204Pb >20.3-20.8, 87Sr/86Sr <0.7033, 143Nd/144Nd >0.5128) and trace element affinities (Ce/Pb 28-36, Nb/U 34-66, Ba/Nb 4-7). The geochemistry of transitional to Q-normative samples from Campbell Island is explained by interaction with continental crust. The volcanism is part of a long-lived (~100 Myr), low-volume, diffuse alkaline magmatic province that includes deposits on the North and South Islands as well as portions of West Antarctica and SE Australia. All of the continental areas were juxtaposed on the eastern margin of Gondwanaland at >83 Ma. A ubiquitous feature of mafic alkaline rocks from this region is their depletion in K and Pb relative to other highly incompatible elements when normalized to primitive mantle values. The inversion of trace element data indicates enriched mantle sources that contain variable proportions of hydrous minerals. We propose that the mantle sources represent continental lithosphere that host amphibole/phlogopite-rich veins formed by plume and/or subduction related metasomatism between 500 and 100 Ma. The strong HIMU signature (206Pb/204Pb >20.5) is considered to be an in-grown feature generated by partial-dehydration and loss of hydrophile elements (Pb, Rb, K) relative to more magmaphile elements (Th, U, Sr) during short-term storage at the base of the lithosphere.
  • Article
    Alteration of volcaniclastic deposits at Minna Bluff : geochemical insights on mineralizing environment and climate during the Late Miocene in Antarctica
    (John Wiley & Sons, 2014-08-19) Antibus, Joanne V. ; Panter, Kurt S. ; Wilch, Thomas I. ; Dunbar, Nelia W. ; McIntosh, William C. ; Tripati, Aradhna K. ; Bindeman, Ilya N. ; Blusztajn, Jerzy S.
    Secondary minerals in volcaniclastic deposits at Minna Bluff, a 45 km long peninsula in the Ross Sea, are used to infer processes of alteration and environmental conditions in the Late Miocene. Glassy volcaniclastic deposits are altered and contain phillipsite and chabazite, low to high-Mg carbonates, chalcedony, and clay. The δ18O of carbonates and chalcedony is variable, ranging from −0.50 to 21.53‰ and 0.68 to 10.37‰, respectively, and δD for chalcedony is light (−187.8 to −220.6‰), corresponding to Antarctic meteoric water. A mean carbonate 87Sr/86Sr ratio of 0.70327 ± 0.0009 (1σ, n = 12) is comparable to lava and suggests freshwater, as opposed to seawater, caused the alteration. Minerals were precipitated at elevated temperatures (91 and 104°C) based on quartz-calcite equilibrium, carbonate 13C-18C thermometry (Δ47 derived temperature = 5° to 43°C) and stability of zeolites in geothermal systems (>10 to ∼100°C). The alteration was a result of isolated, ephemeral events involving the exchange between heated meteoric water and glass during or soon after the formation of each deposit. Near-surface evaporative distillation can explain 18O-enriched compositions for some Mg-rich carbonates and chalcedony. The δ18Owater calculated for carbonates (−15.8 to −22.9‰) reveals a broad change, becoming heavier between ∼12 and ∼7 Ma, consistent with a warming climate. These findings are independently corroborated by the interpretation of Late Miocene sedimentary sequences recovered from nearby sediment cores. However, in contrast to a cold-based thermal regime proposed for ice flow at core sites, wet-based conditions prevailed at Minna Bluff; a likely consequence of high heat flow associated with an active magma system.