(American Geophysical Union, 2024-05-08)
Seltzer, Alan M.; Davidson, Perrin W.; Shackleton, Sarah A.; Nicholson, David P.; Khatiwala, Samar
Quantitative constraints on past mean ocean temperature (MOT) critically inform our historical understanding of Earth's energy balance. A recently developed MOT proxy based on paleoatmospheric Xe, Kr, and N2 ratios in ice core air bubbles is a promising tool rooted in the temperature dependences of gas solubilities. However, these inert gases are systematically undersaturated in the modern ocean interior, and it remains unclear how air-sea disequilibrium may have changed in the past. Here, we carry out 30 tracer-enabled model simulations under varying circulation, sea ice cover, and wind stress regimes to evaluate air-sea disequilibrium in the Last Glacial Maximum (LGM) ocean. We find that undersaturation of all three gases was likely reduced, primarily due to strengthened high-latitude winds, biasing reconstructed MOT by −0.38 ± 0.37°C (1σ). Accounting for air-sea disequilibrium, paleoatmospheric inert gases indicate that LGM MOT was 2.27 ± 0.46°C (1σ) colder than the pre-industrial era.
