Vanko
David A.
Vanko
David A.
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ArticleFluid inclusion evidence for subsurface phase separation and variable fluid mixing regimes beneath the deep-sea PACMANUS hydrothermal field, Manus Basin back arc rift, Papua New Guinea(American Geophysical Union, 2004-03-05) Vanko, David A. ; Bach, Wolfgang ; Roberts, Stephen ; Yeats, Christopher J. ; Scott, Steven D.Altered volcanic rocks were cored from over 350 m below the seafloor at the Papua New Guinea-Australia-Canada Manus Basin Hydrothermal Field (PACMANUS) deep-sea hydrothermal field, in the eastern Manus back arc basin. Fluid inclusions in anhydrite veins reveal phase separation and fluid mixing beneath the seafloor. The anhydrite precipitated from high-temperature fluids (150–385°C). At Roman Ruins, a site of active high-temperature venting (220–276°C, measured by submersible), the fluid inclusion thermal depth profile is uniform and high temperature (242–368°C). At Snowcap, a site of warm water effusion (6–65°C), the fluid inclusions indicate high temperatures at depth (270–385°C) but both low and high temperatures in the shallower section. This indicates a flow regime dominated by vertical advection and shallow entrainment and mixing with cool seawater. Inclusions at Snowcap exhibit extreme salinity variations due to phase separation at temperatures above 350°C. Fluids contain Na, Cl, Fe, Zn, Mg, and Ba and a minor gas component such as CO2 or CH4. Most inclusions at Roman Ruins exhibit salinities that fall within the range of those observed at modern active vent sites along the mid-ocean ridge system. Fluid inclusion temperatures support a hypothesis, developed previously from Sr-isotopic analysis, that the subseafloor at Snowcap is characterized by mixing between deep-sourced hot hydrothermal fluids and cold seawater-like fluid. Both heating of seawater and cooling of upwelling hydrothermal fluids can be recognized by combining isotopic and fluid inclusion data. In contrast to Snowcap, the regime at Roman Ruins is less varied, with uniformly high-temperature upwelling fluids that have hydrothermally dominated Sr-isotopic ratios.
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Working PaperManus 2006 : hydrothermal systems in the Eastern Manus Basin: fluid chemistry and magnetic structure as guides to subseafloor processes(Woods Hole Oceanographic Institution, 2006) Tivey, Maurice A. ; Bach, Wolfgang ; Seewald, Jeffrey S. ; Tivey, Margaret K. ; Vanko, David A.The hydrothermal systems in the Manus Basin of Papua New Guinea (PNG) were comprehensively investigated through a combination of sampling and mapping using the Remotely-Operated Vehicle (ROV) Jason, the autonomous underwater vehicle (AUV) ABE (Autonomous Benthic Explorer) and ship-based CTD work and multi-beam bathymetric mapping using the RV Melville. The objectives of the cruise (July 21st to Sept. 1st, 2006) were to identify the tectonic/geologic settings of the vent systems, examine the interactions of seawater with felsic rocks that constitute the high silica end-member range of seafloor basement compositions, determine the extent of volatile magmatic inputs into these systems and to examine the evolution of hydrothermal activity through time. The first 10-day portion of the cruise was funded by Nautilus Minerals in a collaborative research effort to examine the Manus Spreading Center and the Vienna Woods basalt-hosted hydrothermal vent systems. The second 32-day portion of the cruise, funded by the National Science Foundation (NSF), focused on the felsic-hosted hydrothermal systems of the PACMANUS (Papua New Guinea – Australia – Canada Manus) vents drilled by the Ocean Drilling Program (ODP) in 2000 and the nearby seafloor volcano vent systems of Desmos and SuSu Knolls. Nautilus Minerals generously funded the add-on use of ABE throughout the NSF program allowing for high resolution mapping to be completed on all the major vent sites within the eastern Manus Basin. A total of 30 ROV dives (497 operational hours) were completed collecting 198 vent sulfides, 83 altered substrate and 43 fresh lava samples along with 104 black, gray and clear fluid samples using gastight and major samplers. ABE successfully completed 14 high resolution bathymetric, CTD and magnetic field mapping dives covering a total of 364 line km of seafloor. We located and mapped in detail the Vienna Woods and nearby Tufar-2 and -3 vent areas on Manus Spreading Center documenting the strong tectonic control on the distribution of the vent systems and the presence of reduced magnetization i.e. “magnetic burnholes”, that help define the lateral extent of the vent fields. The Vienna Woods vent systems (273°-285°C) form treetrunk- like chimneys 5-15 m tall, that emit black to gray fluids with pH and compositions similar to other documented midocean ridge (MOR) systems like the East Pacific Rise. At PACMANUS, high-resolution mapping by ABE reveals a distinctive seafloor morphology associated with dacitic lava flows along with discrete magnetic burnholes associated with the active venting systems of Roman Ruins, Satanic Mills, Snowcap, Tsukushi and a new vigorous vent system discovered southeast of the Satanic Mills area named Fenway. Another vent field in its waning stages was also discovered ~8 km northeast of PACMANUS on the Northeast Pual Ridge. At PACMANUS, the 40 m diameter Fenway mound hosts outcrops of massive anhydrite on the seafloor beneath the sulfide chimneys, a rare occurrence as anhydrite is unstable at ambient seafloor conditions. Fenway is also boiling (356°C, 172 bar) with two-phase fluid producing a ”flashing” phenomenon when the Jason lights illuminated the vent orifices. The five PACMANUS vents (271° – 356°C) have ubiquitous low pH (2.3 to 2.8) relative to Vienna Woods and typical MOR fluids, presumably reflecting water-rock reaction with the felsic hosted lava, input of magmatic volatiles and the subsurface deposition of metal sulfides. We investigated two strongly magmatically influenced vent systems associated with seafloor volcanoes. Desmos is a breached caldera with white smokers (70°-115°C) that are highly acidic (pH 1 – 1.5) and sulfur lava flows. SuSu Knolls and the adjacent Suzette mound (Solwara-1 of Nautilus Minerals) were mapped in detail and sampled intensively. Hydrothermal activity at SuSu Knolls showed a remarkable range from boiling black smokers to white sulfur-rich fluids, native sulfur flows and massive anhydrite outcrops. Vent fluids from North Su (48° – 325°C) are 2 characterized by a measured pH of 0.87, more than an order of magnitude more acidic than any deep-sea vent fluid sampled to date. Many of the low pH fluids sampled at North Su and Desmos were actively precipitating native sulfur creating thick plumes of dense white smoke. In general, sampled fluids show a considerable range in pH and gas contents, sometimes within individual hydrothermal fields. The pronounced variability of fluid chemistry within 10’s to 100’s of m at North Su is probably unparalleled in systems studied to date. The most plausible explanation for the observed variability is that different fluid-rock reaction pathways are expressed in regimes of variable magmatic volatile input and extent of subsurface cooling. This hypothesis is supported by the distribution of alteration types at the seafloor, where the occurrence of advanced argillic alteration - that relates to interactions with acid-sulfate waters such as sampled at Desmos and North Su – is patchy and spatially confined to patches of active (Desmos, North Su) and past (Snowcap) venting of such fluids. In relationship to the ODP drilling results at PACMANUS we identified and sampled examples of advanced argillic rock alteration similar to that seen in the drill core. Good examples came from Snowcap and from the North Su pillar. We sampled highly clay-altered basement from just underneath extinct chimney complexes at two locations in the Satanic Mills hydrothermal field. Both samples have dense networks of sulfide veins and may represent the stockwork or feeder zone through which hydrothermal fluids rise up to the seafloor. These samples, in addition to the other altered rock types recovered, will provide useful stepping stones in bridging the knowledge gap between the extensive surface sampling now accomplished and the basement rocks recovered by ODP, where coring was almost nil shallower than 40 m subseafloor depth. Overall, the quality and quantity of solid and fluid samples that can be put in a direct geochemical context is remarkably high. This unique dataset encompasses a broad range of geological environments that includes hydrothermal activity in basalt-hosted oceanic style spreading centers to hydrothermal systems associated with arc-style volcanism. For the first time, alteration assemblages that are commonly observed in drillcore and outcrop on land have been observed in the aqueous environment responsible for their formation.