Ramirez Carlos J.

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Ramirez
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Carlos J.
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  • Article
    Seismic evidence for fluids in fault zones on top of the subducting Cocos Plate beneath Costa Rica
    (John Wiley & Sons, 2010-03-09) Van Avendonk, Harm J. A. ; Holbrook, W. Steven ; Lizarralde, Daniel ; Mora, Mauricio M. ; Harder, Steven H. ; Bullock, Andrew D. ; Alvarado, Guillermo E. ; Ramirez, Carlos J.
    In the 2005 TICOCAVA explosion seismology study in Costa Rica we observed crustal turning waves with a dominant frequency of ~10 Hz on a linear array of short-period seismometers from the Pacific Ocean to the Caribbean Sea. On one of the shot records, from Shot 21 in the backarc of the Cordillera Central, we also observed two seismic phases with an unusually high dominant frequency (~20 Hz). These two phases were recorded in the forearc region of central Costa Rica and arrived ~7 s apart and 30 to 40 s after the detonation of Shot 21. We considered the possibility that these secondary arrivals were produced by a local earthquake that may have happened during the active-source seismic experiment. Such high-frequency phases following Shot 21 were not recorded after Shots 22, 23, and 24, all in the backarc of Costa Rica, which might suggest that they were produced by some other source. However, earthquake dislocation models cannot produce seismic waves of such high frequency with significant amplitude. In addition, we would have expected to see more arrivals from such an earthquake on other seismic stations in central Costa Rica. We therefore investigate whether the high-frequency arrivals may be the result of a deep seismic reflection from the subducting Cocos plate. The timing of these phases is consistent with a shear wave from Shot 21 that was reflected as a compressional (SxP) and a shear (SxS) wave at the top of the subducting Cocos slab between 35 and 55 km depth. The shift in dominant frequency from ~10 Hz in the downgoing seismic wave to ~20 Hz in the reflected waves requires a particular seismic structure at the interface between the subducting slab and the forearc mantle in order to produce a substantial increase in reflection coefficients with frequency. The spectral amplitude characteristics of the SxP and SxS phases from Shot 21 are consistent with a very high Vp/Vs ratio of 6 in ~5 m thick, slab-parallel layers. This result suggests that a system of thin shear zones near the plate interface beneath the forearc is occupied by hydrous fluids under near-lithostatic conditions. The overpressured shear zone probably takes up fluids from the downgoing slab, and it may control the lower limit of the seismogenic zone.
  • Article
    Crustal structure across the Costa Rican Volcanic Arc
    (John Wiley & Sons, 2013-04-29) Hayes, Jorden L. ; Holbrook, W. Steven ; Lizarralde, Daniel ; Van Avendonk, Harm J. A. ; Bullock, Andrew D. ; Mora, Mauricio M. ; Harder, Steven H. ; Alvarado, Guillermo E. ; Ramirez, Carlos J.
    Island arcs are proposed to be essential building blocks for the crustal growth of continents; however, island arcs and continents are fundamentally different in bulk composition: mafic and felsic, respectively. The substrate upon which arcs are built (oceanic crust versus large igneous province) may have a strong influence on crustal genesis. We present results from an across-arc wide-angle seismic survey of the Costa Rican volcanic front which test the hypothesis that juvenile continental crust is actively forming at this location. Travel-time tomography constrains velocities in the upper arc to a depth of ~15 km where average velocities are <6.5 km/s. The upper 5 km of crust is constrained by velocities between 4.0 and 5.5 km/s, which likely represent sediments, volcaniclastics, flows, and small intrusions. Between 5 and 15 km depth, velocities increase slowly from 5.5 to 6.5 km/s. Crustal thickness and lower crustal velocities are roughly constrained by reflections from an inferred crust-mantle transition zone. Crustal thickness beneath the volcanic front in Costa Rica is ~40 km with best-fit average lower-crustal velocities between 6.8 and 7.1 km/s. Overall, velocities across the arc in central Costa Rica are at the high-velocity extreme of bulk continental crust velocities and are lower than modern island arc velocities, suggesting that continental compositions are created at this location. These data suggest that preexisting thick crust of the Caribbean Large Igneous Province has a measurable effect on bulk composition. This thickened arc crust may be a density filter for mafic material and thereby support differentiation toward continental compositions.
  • Article
    The helium and carbon isotope characteristics of the Andean Convergent Margin
    (Frontiers Media, 2022-06-13) Barry, Peter H. ; de Moor, J. Maarten ; Chiodi, Agostina ; Aguilera, Felipe ; Hudak, Michael R. ; Bekaert, David V. ; Turner, Stephen ; Curtice, Joshua ; Seltzer, Alan M. ; Jessen, Gerdhard L. ; Osses, Esteban ; Blamey, Jenny M. ; Amenabar, Maximiliano J. ; Selci, Matteo ; Cascone, Martina ; Bastianoni, Alessia ; Nakagawa, Mayuko ; Filipovich, Rubén ; Bustos, Emilce ; Schrenk, Matthew O. ; Buongiorno, Joy ; Ramirez, Carlos J. ; Rogers, Timothy J. ; Lloyd, Karen G. ; Giovannelli, Donato
    Subduction zones represent the interface between Earth’s interior (crust and mantle) and exterior (atmosphere and oceans), where carbon and other volatile elements are actively cycled between Earth reservoirs by plate tectonics. Helium is a sensitive tracer of volatile sources and can be used to deconvolute mantle and crustal sources in arcs; however it is not thought to be recycled into the mantle by subduction processes. In contrast, carbon is readily recycled, mostly in the form of carbon-rich sediments, and can thus be used to understand volatile delivery via subduction. Further, carbon is chemically-reactive and isotope fractionation can be used to determine the main processes controlling volatile movements within arc systems. Here, we report helium isotope and abundance data for 42 deeply-sourced fluid and gas samples from the Central Volcanic Zone (CVZ) and Southern Volcanic Zone (SVZ) of the Andean Convergent Margin (ACM). Data are used to assess the influence of subduction parameters (e.g., crustal thickness, subduction inputs, and convergence rate) on the composition of volatiles in surface volcanic fluid and gas emissions. He isotopes from the CVZ backarc range from 0.1 to 2.6 RA (n = 23), with the highest values in the Puna and the lowest in the Sub-Andean foreland fold-and-thrust belt. Atmosphere-corrected He isotopes from the SVZ range from 0.7 to 5.0 RA (n = 19). Taken together, these data reveal a clear southeastward increase in 3He/4He, with the highest values (in the SVZ) falling below the nominal range associated with pure upper mantle helium (8 ± 1 RA), approaching the mean He isotope value for arc gases of (5.4 ± 1.9 RA). Notably, the lowest values are found in the CVZ, suggesting more significant crustal inputs (i.e., assimilation of 4He) to the helium budget. The crustal thickness in the CVZ (up to 70 km) is significantly larger than in the SVZ, where it is just ∼40 km. We suggest that crustal thickness exerts a primary control on the extent of fluid-crust interaction, as helium and other volatiles rise through the upper plate in the ACM. We also report carbon isotopes from (n = 11) sites in the CVZ, where δ13C varies between −15.3‰ and −1.2‰ [vs. Vienna Pee Dee Belemnite (VPDB)] and CO2/3He values that vary by over two orders of magnitude (6.9 × 108–1.7 × 1011). In the SVZ, carbon isotope ratios are also reported from (n = 13) sites and vary between −17.2‰ and −4.1‰. CO2/3He values vary by over four orders of magnitude (4.7 × 107–1.7 × 1012). Low δ13C and CO2/3He values are consistent with CO2 removal (e.g., calcite precipitation and gas dissolution) in shallow hydrothermal systems. Carbon isotope fractionation modeling suggests that calcite precipitation occurs at temperatures coincident with the upper temperature limit for life (122°C), suggesting that biology may play a role in C-He systematics of arc-related volcanic fluid and gas emissions.
  • Article
    Complex organic matter degradation by secondary consumers in chemolithoautotrophy-based subsurface geothermal ecosystems
    (Public Library of Science, 2023-08-18) Paul, Raegan ; Rogers, Timothy J. ; Fullerton, Kate M. ; Selci, Matteo ; Cascone, Martina ; Stokes, Murray H. ; Steen, Andrew D. ; de Moor, J. Maarten ; Chiodi, Agostina ; Stefansson, Andri ; Halldorsson, Saemundur ; Ramirez, Carlos J. ; Jessen, Gerdhard L. ; Barry, Peter H. ; Cordone, Angelina ; Giovannelli, Donato ; Lloyd, Karen G.
    Microbial communities in terrestrial geothermal systems often contain chemolithoautotrophs with well-characterized distributions and metabolic capabilities. However, the extent to which organic matter produced by these chemolithoautotrophs supports heterotrophs remains largely unknown. Here we compared the abundance and activity of peptidases and carbohydrate active enzymes (CAZymes) that are predicted to be extracellular identified in metagenomic assemblies from 63 springs in the Central American and the Andean convergent margin (Argentinian backarc of the Central Volcanic Zone), as well as the plume-influenced spreading center in Iceland. All assemblies contain two orders of magnitude more peptidases than CAZymes, suggesting that the microorganisms more often use proteins for their carbon and/or nitrogen acquisition instead of complex sugars. The CAZy families in highest abundance are GH23 and CBM50, and the most abundant peptidase families are M23 and C26, all four of which degrade peptidoglycan found in bacterial cells. This implies that the heterotrophic community relies on autochthonous dead cell biomass, rather than allochthonous plant matter, for organic material. Enzymes involved in the degradation of cyanobacterial- and algal-derived compounds are in lower abundance at every site, with volcanic sites having more enzymes degrading cyanobacterial compounds and non-volcanic sites having more enzymes degrading algal compounds. Activity assays showed that many of these enzyme classes are active in these samples. High temperature sites (> 80°C) had similar extracellular carbon-degrading enzymes regardless of their province, suggesting a less well-developed population of secondary consumers at these sites, possibly connected with the limited extent of the subsurface biosphere in these high temperature sites. We conclude that in < 80°C springs, chemolithoautotrophic production supports heterotrophs capable of degrading a wide range of organic compounds that do not vary by geological province, even though the taxonomic and respiratory repertoire of chemolithoautotrophs and heterotrophs differ greatly across these regions.