Martínez Méndez
Gema
Martínez Méndez
Gema
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ArticleCalibration of the carbon isotope composition (δ13C) of benthic foraminifera(John Wiley & Sons, 2017-06-03) Schmittner, Andreas ; Bostock, Helen ; Cartapanis, olivier ; Curry, William B. ; Filipsson, Helena L. ; Galbraith, Eric D. ; Gottschalk, Julia ; Herguera, Juan Carlos ; Hoogakker, Babette ; Jaccard, Samuel L. ; Lisiecki, Lorraine E. ; Lund, David C. ; Martínez Méndez, Gema ; Lynch-Stieglitz, Jean ; Mackensen, Andreas ; Michel, Elisabeth ; Mix, Alan C. ; Oppo, Delia W. ; Peterson, Carlye D. ; Repschläger, Janne ; Sikes, Elisabeth L. ; Spero, Howard J. ; Waelbroeck, ClaireThe carbon isotope composition (δ13C) of seawater provides valuable insight on ocean circulation, air-sea exchange, the biological pump, and the global carbon cycle and is reflected by the δ13C of foraminifera tests. Here more than 1700 δ13C observations of the benthic foraminifera genus Cibicides from late Holocene sediments (δ13CCibnat) are compiled and compared with newly updated estimates of the natural (preindustrial) water column δ13C of dissolved inorganic carbon (δ13CDICnat) as part of the international Ocean Circulation and Carbon Cycling (OC3) project. Using selection criteria based on the spatial distance between samples, we find high correlation between δ13CCibnat and δ13CDICnat, confirming earlier work. Regression analyses indicate significant carbonate ion (−2.6 ± 0.4) × 10−3‰/(μmol kg−1) [CO32−] and pressure (−4.9 ± 1.7) × 10−5‰ m−1 (depth) effects, which we use to propose a new global calibration for predicting δ13CDICnat from δ13CCibnat. This calibration is shown to remove some systematic regional biases and decrease errors compared with the one-to-one relationship (δ13CDICnat = δ13CCibnat). However, these effects and the error reductions are relatively small, which suggests that most conclusions from previous studies using a one-to-one relationship remain robust. The remaining standard error of the regression is generally σ ≅ 0.25‰, with larger values found in the southeast Atlantic and Antarctic (σ ≅ 0.4‰) and for species other than Cibicides wuellerstorfi. Discussion of species effects and possible sources of the remaining errors may aid future attempts to improve the use of the benthic δ13C record.
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ArticleIsotopic characterization of water masses in the Southeast Pacific Region: paleoceanographic implications(American Geophysical Union, 2021-12-23) Reyes-Macaya, Dharma ; Hoogakker, Babette ; Martínez-Méndez, Gema ; Llanillo, Pedro J. ; Grasse, Patricia ; Mohtadi, Mahyar ; Mix, Alan C. ; Leng, Melanie J. ; Struck, Ulrich ; McCorkle, Daniel C. ; Troncoso, Macarena ; Gayo, Eugenia M. ; Lange, Carina B. ; Farias, Laura ; Carhuapoma, Wilson ; Graco, Michelle ; Cornejo-D’Ottone, Marcela ; De Pol-Holz, Ricardo ; Fernandez, Camila ; Narváez, Diego ; Vargas, Cristian A. ; García-Araya, Francisco ; Hebbeln, DierkIn this study, we used stable isotopes of oxygen (δ18O), deuterium (δD), and dissolved inorganic carbon (δ13CDIC) in combination with temperature, salinity, oxygen, and nutrient concentrations to characterize the coastal (71°–78°W) and an oceanic (82°–98°W) water masses (SAAW—Subantarctic Surface Water; STW—Subtropical Water; ESSW—Equatorial Subsurface water; AAIW—Antarctic Intermediate Water; PDW—Pacific Deep Water) of the Southeast Pacific (SEP). The results show that δ18O and δD can be used to differentiate between SAAW-STW, SAAW-ESSW, and ESSW-AAIW. δ13CDIC signatures can be used to differentiate between STW-ESSW (oceanic section), SAAW-ESSW, ESSW-AAIW, and AAIW-PDW. Compared with the oceanic section, our new coastal section highlights differences in both the chemistry and geometry of water masses above 1,000 m. Previous paleoceanographic studies using marine sediments from the SEP continental margin used the present-day hydrological oceanic transect to compare against, as the coastal section was not sufficiently characterized. We suggest that our new results of the coastal section should be used for past characterizations of the SEP water masses that are usually based on continental margin sediment samples.
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ArticleConsistently dated Atlantic sediment cores over the last 40 thousand years(Nature Research, 2019-09-02) Waelbroeck, Claire ; Lougheed, Bryan C. ; Vazquez Riveiros, Natalia ; Missiaen, Lise ; Pedro, Joel ; Dokken, Trond ; Hajdas, Irka ; Wacker, Lukas ; Abbott, Peter ; Dumoulin, Jean-Pascal ; Thil, Francois ; Eynaud, Frederique ; Rossignol, Linda ; Fersi, Wiem ; Albuquerque, Ana Luiza ; Arz, Helge W. ; Austin, William E. N. ; Came, Rosemarie E. ; Carlson, Anders E. ; Collins, James A. ; Dennielou, Bernard ; Desprat, Stéphanie ; Dickson, Alex ; Elliot, Mary ; Farmer, Christa ; Giraudeau, Jacques ; Gottschalk, Julia ; Henderiks, Jorijntje ; Hughen, Konrad A. ; Jung, Simon ; Knutz, Paul ; Lebreiro, Susana ; Lund, David C. ; Lynch-Stieglitz, Jean ; Malaizé, Bruno ; Marchitto, Thomas M. ; Martínez-Méndez, Gema ; Mollenhauer, Gesine ; Naughton, Filipa ; Nave, Silvia ; Nürnberg, Dirk ; Oppo, Delia W. ; Peck, Vicky L. ; Peeters, Frank J. C. ; Penaud, Aurélie ; Portilho-Ramos, Rodrigo da Costa ; Repschläger, Janne ; Roberts, Jenny ; Ruhlemann, Carsten ; Salgueiro, Emilia ; Sanchez Goni, Maria Fernanda ; Schönfeld, Joachim ; Scussolini, Paolo ; Skinner, Luke C. ; Skonieczny, Charlotte ; Thornalley, David J. R. ; Toucanne, Samuel ; Van Rooij, David ; Vidal, Laurence ; Voelker, Antje H. L. ; Wary, Mélanie ; Weldeab, Syee ; Ziegler, MartinRapid changes in ocean circulation and climate have been observed in marine-sediment and ice cores over the last glacial period and deglaciation, highlighting the non-linear character of the climate system and underlining the possibility of rapid climate shifts in response to anthropogenic greenhouse gas forcing. To date, these rapid changes in climate and ocean circulation are still not fully explained. One obstacle hindering progress in our understanding of the interactions between past ocean circulation and climate changes is the difficulty of accurately dating marine cores. Here, we present a set of 92 marine sediment cores from the Atlantic Ocean for which we have established age-depth models that are consistent with the Greenland GICC05 ice core chronology, and computed the associated dating uncertainties, using a new deposition modeling technique. This is the first set of consistently dated marine sediment cores enabling paleoclimate scientists to evaluate leads/lags between circulation and climate changes over vast regions of the Atlantic Ocean. Moreover, this data set is of direct use in paleoclimate modeling studies.
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ArticleStable oxygen isotopes and Mg/Ca in planktic foraminifera from modern surface sediments of the Western Pacific Warm Pool : implications for thermocline reconstructions(John Wiley & Sons, 2017-11-09) Hollstein, Martina ; Mohtadi, Mahyar ; Rosenthal, Yair ; Sanchez, Paola Moffa ; Oppo, Delia W. ; Martínez Méndez, Gema ; Steinke, Stephan ; Hebbeln, DierkMg/Ca and stable oxygen isotope compositions (δ18O) of planktic foraminifera tests are commonly used as proxies to reconstruct past ocean conditions including variations in the vertical water column structure. Accurate proxy calibrations require thorough regional studies, since parameters such as calcification depth and temperature of planktic foraminifera depend on local environmental conditions. Here we present radiocarbon-dated, modern surface sediment samples and water column data (temperature, salinity, and seawater δ18O) from the Western Pacific Warm Pool. Seawater δ18O (δ18OSW) and salinity are used to calculate individual regressions for western Pacific surface and thermocline waters (δ18OSW = 0.37 × S-12.4 and δ18OSW = 0.33 × S-11.0). We combine shell δ18O and Mg/Ca with water column data to estimate calcification depths of several planktic foraminifera and establish regional Mg/Ca-temperature calibrations. Globigerinoides ruber, Globigerinoides elongatus, and Globigerinoides sacculifer reflect mixed layer conditions. Pulleniatina obliquiloculata and Neogloboquadrina dutertrei and Globorotalia tumida preserve upper and lower thermocline conditions, respectively. Our multispecies Mg/Ca-temperature calibration (Mg/Ca = 0.26exp0.097*T) matches published regressions. Assuming the same temperature sensitivity in all species, we propose species-specific calibrations that can be used to reconstruct upper water column temperatures. The Mg/Ca temperature dependencies of G. ruber, G. elongatus, and G. tumida are similar to published equations. However, our data imply that calcification temperatures of G. sacculifer, P. obliquiloculata, and N. dutertrei are exceptionally warm in the western tropical Pacific and thus underestimated by previously published calibrations. Regional Mg/Ca-temperature relations are best described by Mg/Ca = 0.24exp0.097*T for G. sacculifer and by Mg/Ca = 0.21exp0.097*T for P. obliquiloculata and N. dutertrei.