Mercury species concentrations and fluxes in the Central Tropical Pacific Ocean
Munson, Kathleen M.
Lamborg, Carl H.
Swarr, Gretchen J.
Saito, Mak A.
MetadataShow full item record
The formation of the toxic and bioaccumulating monomethylmercury (MMHg) in marine systems is poorly understood, due in part to sparse data from many ocean regions. We present dissolved mercury (Hg) speciation data from 10 stations in the North and South Equatorial Pacific spanning large water mass differences and gradients in oxygen utilization. We also compare the mercury content in suspended particles from six stations and sinking particles from three stations to constrain local Hg sources and sinks. Concentrations of total Hg (THg) and methylated Hg in the surface and intermediate waters of the Equatorial and South Pacific suggest Hg cycling distinct from that of the North Pacific gyre. Maximum concentrations of 180 fM for both MMHg and dimethylmercury (DMHg) are observed in the Equatorial Pacific. South of the equator, concentrations of MMHg and DMHg are less than 100 fM. Sinking fluxes of particulate THg can reasonably explain the shape of dissolved THg profiles, but those of MMHg are too low to account for dissolved MMHg profiles. However, methylated Hg species are lower than predicted from remineralization rates based on North Pacific data, consistent with limitation of methylation in Equatorial and South Pacific waters. Full water column depth profiles were also measured for the first time in these regions. Concentrations of THg are elevated in deep waters of the North Pacific, compared to those in the intermediate and surface waters, and taper off in the South Pacific. Comparisons with previous measurements from nearby regions suggest little enrichment of THg or MMHg over the past 20 years.
Author Posting. © American Geophysical Union, 2015. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 29 (2015): 656–676, doi:10.1002/2015GB005120.
Suggested CitationArticle: Munson, Kathleen M., Lamborg, Carl H., Swarr, Gretchen J., Saito, Mak A., "Mercury species concentrations and fluxes in the Central Tropical Pacific Ocean", Global Biogeochemical Cycles 29 (2015): 656–676, DOI:10.1002/2015GB005120, https://hdl.handle.net/1912/7387
Showing items related by title, author, creator and subject.
Microbial- and thiosulfate-mediated dissolution of mercury sulfide minerals and transformation to gaseous mercury Vazquez-Rodriguez, Adiari I.; Hansel, Colleen M.; Zhang, Tong; Lamborg, Carl H.; Santelli, Cara M.; Webb, Samuel M.; Brooks, Scott C. (Frontiers Media, 2015-06-23)Mercury (Hg) is a toxic heavy metal that poses significant environmental and human health risks. Soils and sediments, where Hg can exist as the Hg sulfide mineral metacinnabar (β-HgS), represent major Hg reservoirs in ...
Atmospheric mercury and fine particulate matter in coastal New England : implications for mercury and trace element sources in the northeastern United States Kolker, Allan; Engle, Mark A.; Peucker-Ehrenbrink, Bernhard; Geboy, Nicholas J.; Krabbenhoft, David P.; Bothner, Michael H.; Tate, Michael T. (Elsevier B.V., 2013-08-29)Intensive sampling of ambient atmospheric fine particulate matter was conducted at Woods Hole, Massachusetts over a four-month period from 3 April to 29 July, 2008, in conjunction with year-long deployment of the USGS ...
An intercomparison of procedures for the determination of total mercury in seawater and recommendations regarding mercury speciation during GEOTRACES cruises Lamborg, Carl H.; Hammerschmidt, Chad R.; Gill, Gary A.; Mason, Robert P.; Gichuki, Susan (Association for the Sciences of Limnology and Oceanography, 2012-02)We conducted a laboratory intercomparison of total mercury (Hg) determination in seawater collected during U.S. GEOTRACES Intercalibration cruises in 2008 and 2009 to the NW Atlantic and NE Pacific Oceans. Results indicated ...