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dc.contributor.authorBurke, Andrea  Concept link
dc.contributor.authorPresent, Theodore M.  Concept link
dc.contributor.authorParis, Guillaume  Concept link
dc.contributor.authorRae, Emily C. M.  Concept link
dc.contributor.authorSandilands, Brodie H.  Concept link
dc.contributor.authorGaillardet, Jerome  Concept link
dc.contributor.authorPeucker-Ehrenbrink, Bernhard  Concept link
dc.contributor.authorFischer, Woodward W.  Concept link
dc.contributor.authorMcClelland, James W.  Concept link
dc.contributor.authorSpencer, Robert G. M.  Concept link
dc.contributor.authorVoss, Britta M.  Concept link
dc.contributor.authorAdkins, Jess F.  Concept link
dc.date.accessioned2018-07-31T16:18:21Z
dc.date.available2018-07-31T16:18:21Z
dc.date.issued2018-05
dc.identifier.urihttps://hdl.handle.net/1912/10503
dc.descriptionAuthor Posting. © The Author(s), 2018. This is the author's version of the work. It is posted here under a nonexclusive, irrevocable, paid-up, worldwide license granted to WHOI. It is made available for personal use, not for redistribution. The definitive version was published in Earth and Planetary Science Letters 496 (2018): 168-177, doi:10.1016/j.epsl.2018.05.022.en_US
dc.description.abstractThe biogeochemical sulfur cycle is intimately linked to the cycles of carbon, iron, and oxygen, and plays an important role in global climate via weathering reactions and aerosols. However, many aspects of the modern budget of the global sulfur cycle are not fully understood. We present new δ34S measurements on sulfate from more than 160 river samples from different geographical and climatic regions—more than 46% of the world’s freshwater flux to the ocean is accounted for in this estimate of the global riverine sulfur isotope budget. These measurements include major rivers and their tributaries, as well as time series, and are combined with previously published data to estimate the modern flux-weighted global riverine δ34S as 4.4 ± 4.5 ‰ (V-CDT), and 4.8 ± 4.9 ‰ when the most polluted rivers are excluded. Combined with major anion and cation concentrations, the sulfur isotope data allow us to tease apart the relative contributions of different processes to the modern riverine sulfur budget, resulting in new estimates of the flux of riverine sulfate due to the oxidative weathering of pyrites (1.3 ± 0.2 Tmol S/y) and the weathering of sedimentary sulfate minerals (1.5 ± 0.2 Tmol S/y). These data indicate that previous estimates of the global oxidative weathering of pyrite have been too low by a factor of two. As pyrite oxidation coupled to carbonate weathering can act as a source of CO2 to the atmosphere, this global pyrite weathering budget implies that the global CO2 weathering sink is overestimated. Furthermore, the large range of sulfur isotope ratios in modern rivers indicates that secular changes in the lithologies exposed to weathering through time could play a major role in driving past variations in δ34S of seawater.en_US
dc.description.sponsorshipThis research was funded by a Foster and Coco Stanback postdoctoral fellowship and a Marie Curie Career Integration Grant (CIG14-631752) to AB. JFA acknowledges the support of NSF-OCE grant 1340174 and NSF-EAR grant 1349858. WF acknowledges the support of a grant from the David and Lucile Packard Foundation.en_US
dc.language.isoen_USen_US
dc.relation.urihttps://doi.org/10.1016/j.epsl.2018.05.022
dc.subjectSulfuren_US
dc.subjectRiversen_US
dc.subjectWeatheringen_US
dc.subjectPyriteen_US
dc.titleSulfur isotopes in rivers : insights into global weathering budgets, pyrite oxidation, and the modern sulfur cycleen_US
dc.typePreprinten_US


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