Thorium speciation in seawater
Santschi, Peter H.
Murray, James W.
Benitez-Nelson, Claudia R.
Guo, L. D.
Lamborg, Carl H.
Moran, S. Bradley
MetadataShow full item record
KeywordThorium; Speciation; Seawater; Colloids; Exopolymeric substances; Transparent exopolymeric particles; Amphiphiles; Biosurfactant ligand
Since the 1960’s, thorium isotopes occupy a special place in the oceanographer’s toolbox as tracers for determining rates and mechanisms of oceanic scavenging, particle dynamics, and carbon fluxes. Due to their unique and constant production rates from soluble parent nuclides of uranium and radium, their disequilibrium can be used to calculate rates and time scales of sinking particles. In addition, by ratio-ing particulate 234Th (as well, in principle, other Thnuclides) to carbon (and other elements), and linking this ratio to the parent-daughter disequilibrium in the water column, it is possible to calculate fluxes of carbon and other elements. Most of these applications are possible with little knowledge of the dissolved chemical properties of thorium, other than its oxidation state (IV) and tendency to strongly sorb to surfaces, i.e., its “particle- or surface-activity”. However, the use of any tracer is hindered by a lack of knowledge of its chemical properties. Recent observations in the variability of carbon to 234Th ratios in different particle types, as well as of associations of Th(IV) with various marine organic biomolecules has led to the need for a review of current knowledge and what future endeavors should be taken to understand the marine chemistry of thorium.
Author Posting. © The Authors, 2006. This is the author's version of the work. It is posted here by permission of Elsevier B.V. for personal use, not for redistribution. The definitive version was published in Marine Chemistry 100 (2006): 250-268, doi:10.1016/j.marchem.2005.10.024.
Suggested CitationPreprint: Santschi, Peter H., Murray, James W., Baskaran, Mark, Benitez-Nelson, Claudia R., Guo, L. D., Hung, C.-C., Lamborg, Carl H., Moran, S. Bradley, Passow, Uta, Roy-Barman, Matthieu, "Thorium speciation in seawater", 2005-07, https://doi.org/10.1016/j.marchem.2005.10.024, https://hdl.handle.net/1912/1043
Showing items related by title, author, creator and subject.
Improvements to 232-thorium, 230-thorium, and 231- protactinium analysis in seawater arising from GEOTRACES intercalibration Auro, Maureen E.; Robinson, Laura F.; Burke, Andrea; Bradtmiller, Louisa I.; Fleisher, Martin Q.; Anderson, Robert F. (Association for the Sciences of Limnology and Oceanography, 2012-07)The GEOTRACES program requires the analysis of large numbers of seawater samples for 232Th, 230Th, and 231Pa. During the GEOTRACES international intercalibration exercise, we encountered unexpected difficulties with recovery ...
Cai, Pinghe; Dai, Minhan; Lv, Dongwei; Chen, Weifang (2005-06-09)The recently developed 2‐5 L small‐volume MnO2 coprecipitation method for determining 234Th in seawater has provided a new way to substantially increase, both temporally and spatially, the sampling resolution of 234Th ...
Hartman, M. C.; Buesseler, Ken O. (Woods Hole Oceanographic Institution, 1994-07)Two polypropylene cartridge types (Beta Pure and Hytrex II) were tested in the laboratory as adsorbers for in-situ collection of dissolved Thorium-234 (234TH) in seawater. Using a uranyl nitrate tracer, we determined that ...