An improvement in the small-volume technique for determining thorium-234 in seawater
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The recently developed 2‐5 L small‐volume MnO2 coprecipitation method for determining 234Th in seawater has provided a new way to substantially increase, both temporally and spatially, the sampling resolution of 234Th and 234Th‐based particulate organic carbon export estimates in the upper ocean. In this study, we further optimize the technique by reducing reagent quantities and the use of an additional water bath heating step. This optimization allows the filtration of the MnO2 precipitate onto a 25‐mm diameter, 1.0 μm pore size QMA filter to be completed within < 30 minutes for unfiltered waters from the South China Sea. In addition, we have modified the MnO2 purification procedure to allow for alpha spetrometric measurements of 234Th recoveries. Results from recovery experiments suggest that reagent amounts can be reduced to 0.0375 mg KMnO4 and 0.1 mg MnCl2∙4H2O per liter of sample, while still maintaining high 234Th recovery. This study further confirms that the addition of a yield monitor is necessary for the application of this small‐volume method.
Author Posting. © The Authors, 2005. This is the author's version of the work. It is posted here by permission of Elsevier B.V. for personal use, not for redistribution. The definitive version was published in Marine Chemistry 100 (2006): 282-288, doi:10.1016/j.marchem.2005.10.016.
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Buesseler, Ken O.; McDonnell, Andrew M. P.; Schofield, Oscar M. E.; Steinberg, Deborah K.; Ducklow, Hugh W. (American Geophysical Union, 2010-11-24)Drifting cylindrical traps and the flux proxy 234Th indicate more than an order of magnitude higher sinking fluxes of particulate carbon and 234Th in January 2009 than measured by a time-series conical trap used regularly ...
Anderson, Robert F. (Massachusetts Institute of Technology and Woods Hole Oceanographic Institution, 1980-11)Suspended particulate matter was collected by sediment traps deployed in the Sargasso Sea (Site S2), the north equatorial Atlantic (Site E), the north equatorial Pacific (Site P), and the Panama Basin (STIE Site). Additional ...
Hartman, M. C.; Buesseler, Ken O. (Woods Hole Oceanographic Institution, 1994-07)Two polypropylene cartridge types (Beta Pure and Hytrex II) were tested in the laboratory as adsorbers for in-situ collection of dissolved Thorium-234 (234TH) in seawater. Using a uranyl nitrate tracer, we determined that ...