Compound Quantitative Geographic Concentration Highest Reproducibility Ions (m/z) Distribution Range (pg/ml) Blank Level (±pg/ml) (pg/ml) tremetone 202 S,H,P,D,K 2-102 0 1-46 sugiol 285, 300 S 1-3 0 1 dehydroabietane 255, 270 S 2-3 0 1 dehydroabietic aldehyde 269, 284 S 1-3 0 ~0 fluoranthene 202 S,H,P,D,K 0-2 1 0-1 pyrene 202 S,H,P,D,K 0-8 1 0-2 dodecanoic acid (C12) 60, 129 S,P,D,K 147-721 6705 130-374 tridecanoic acid (C13) 60, 129 S 83 0 26 tetradecanoic acid (C14) 60, 129 S,P,D,K 160-700 196 111-295 pentadecanoic acid (C15) 60, 129 S 174 48 47 hexadecanoic acid (C16) 60, 129 S,P,D 267-2345 537 673-3511 octadecenoic acid (C18:1) 55, 69 S 1710 0 580 octadecanoic acid (C18) 60, 129 S 3178 269 3275 tetradecanamide (C14) 59, 72 P,D,K 9-608 49 1-404 hexadecenamide (C16:1) 59, 72 S,H,P,D,K 5-870 14 1-262 hexadecanamide (C16) 59, 72 S,H,P,D,K 49-1390 196 16-694 octadecenamide (C18:1) 59, 72 S,H,P,D,K 20-7619 139 37-5479 octadecanamide (C18) 59, 72 S,H,P,D,K 19-1026 0 5-509 eicosenamide (C20:1) 59, 72 S,H,P,D,K 5-50 0 0-26 docosenamide (C22:1) 59, 72 S,H,P,D,K 294-1459 0 60-1015 N,N- dimethyloctanamide 87 S,H,D,K 3-226 0 7-113 hexadecenenitrile (C16:1) 122, 136 S,H,P,D,K 3-63 0 0-25 hexadecanenitrile (C16) 97, 110 S,H,P,D,K 6-44 18 1-22 octadecenenitrile (C18:1) 122, 136 S,H,P,D,K 10-262 24 4-182 docosenenitrile (C22:1) 122, 136 S,H,P,D,K 9-82 0 4-57 total n-alkanes (C21-C34) 71, 85 S,H,P,D,K ~0-19 ng/ml 459 ng/ml 89-1275