http://lod.bco-dmo.org/id/dataset/867007
eng; USA
utf8
dataset
Highest level of data collection, from a common set of sensors or instrumentation, usually within the same research project
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
pointOfContact
2021-12-22
ISO 19115-2 Geographic Information - Metadata - Part 2: Extensions for Imagery and Gridded Data
ISO 19115-2:2009(E)
Porewater geochemistry of sediments collected Fall 2019 in the Santa Barbara Basin using ROV Jason during R/V Atlantis cruise AT42-19
2021-12-23
publication
2021-12-23
revision
Marine Biological Laboratory/Woods Hole Oceanographic Institution Library (MBLWHOI DLA)
2022-02-08
publication
https://doi.org/10.26008/1912/bco-dmo.867007.1
Tina Treude
University of California-Los Angeles
principalInvestigator
David L. Valentine
University of California-Santa Barbara
principalInvestigator
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
publisher
Cite this dataset as: Treude, T., Valentine, D. L. (2021) Porewater geochemistry of sediments collected Fall 2019 in the Santa Barbara Basin using ROV Jason during R/V Atlantis cruise AT42-19. Biological and Chemical Oceanography Data Management Office (BCO-DMO). (Version 1) Version Date 2021-12-23 [if applicable, indicate subset used]. doi:10.26008/1912/bco-dmo.867007.1 [access date]
Geochemical porewater data from sediments collected along three depth transects across the Santa Barbara Basin Dataset Description: Acquisition Description: <p>Sediments were collected with push cores (6 cm inner diameter) along three depth transects across the Santa Barbara Basin using the ROV Jason.&nbsp; Porewater was separated from sediment by centrifugation (4300 x g for 20 mins) in anoxic centrifugation vials and subsampled for further analysis.&nbsp;</p>
<p>Porewater geochemical properties were determined as listed:</p>
<ul>
<li>Porewater sulfate concentrations were determined by ion chromatography (Metrohm 761).</li>
<li>Porewater sulfide concentrations were determined spectrophotometrically (Shimadzu UV-Spectrophotometer UV-1800) according to Cline (1969).</li>
<li>Porewater ammonium, iron (II), and phosphate concentrations were determined spectrophotometrically (Shimadzu UV-Spectrophotometer UV-1800) according to Grasshoff et al. (1999).</li>
<li>Porewater nitrate and nitrite concentrations were determined spectrophotometrically (Shimadzu UV-Spectrophotometer UV-1800) according to García-Robledo et al. (2014).</li>
<li>Porewater Total Alkalinity was determined by titration according to Dale et al. 2015. Porewater Dissolved Inorganic Carbon was determined using a flow injection system (Hall &amp; Aller 1992).</li>
</ul>
<p>Note:&nbsp; Negative depths refer to measurements in the sediment core supernatant water.&nbsp; Supernatant water was collected with an anoxic syringe prior to core slicing.&nbsp;</p>
Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-1829981 Award URL: http://www.nsf.gov/awardsearch/showAward.do?AwardNumber=1829981
Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-1830033 Award URL: http://www.nsf.gov/awardsearch/showAward.do?AwardNumber=1830033
completed
Tina Treude
University of California-Los Angeles
310-267-5213
Department of Earth, Planetary, and Space Sciences 595 Charles E. Young Drive, East
Los Angeles
CA
90095-1567
USA
ttreude@g.ucla.edu
pointOfContact
David L. Valentine
University of California-Santa Barbara
805-893-2973
Department of Earth Science 1006 Webb Hall
Santa Barbara
CA
93106
USA
valentine@geol.ucsb.edu
pointOfContact
asNeeded
Dataset Version: 1
Unknown
Cruise
Location
Latitude
Longitude
ISO_DateTime_UTC
Station
Water_Depth
Sampling_Instrument
Sediment_Depth
Total_Alkalinity
DIC
Iron_II
Total_Sulfide
Sulfate
Ammonium
Nitrate
Nitrite
Phosphate
Gravity Core
Shimadzu UV-Spectrophotometer UV-1800
ROV Jason
flow injection system
Metrohm 761
ROV push cores
centrifuge
theme
None, User defined
cruise id
region
latitude
longitude
ISO_DateTime_UTC
station
depth
instrument
depth below seafloor
total alkalinity (TA)
dissolved inorganic Carbon
Iron
sulfide
sulfate
Ammonium
Nitrate
Nitrite
phosphate
featureType
BCO-DMO Standard Parameters
Gravity Corer
UV Spectrophotometer-Shimadzu
ROV Jason
Flow Injection Analyzer
Ion Chromatograph
Push Corer
Centrifuge
instrument
BCO-DMO Standard Instruments
AT42-19
service
Deployment Activity
Santa Barbara Basin, California, northeast Pacific Ocean
place
Locations
otherRestrictions
otherRestrictions
Access Constraints: none. Use Constraints: Please follow guidelines at: http://www.bco-dmo.org/terms-use Distribution liability: Under no circumstances shall BCO-DMO be liable for any direct, incidental, special, consequential, indirect, or punitive damages that result from the use of, or the inability to use, the materials in this data submission. If you are dissatisfied with any materials in this data submission your sole and exclusive remedy is to discontinue use.
Collaborative Research: Do benthic feedbacks couple sulfur, nitrogen and carbon biogeochemistry during transient deoxygenation?
https://www.bco-dmo.org/project/810831
Collaborative Research: Do benthic feedbacks couple sulfur, nitrogen and carbon biogeochemistry during transient deoxygenation?
<p>NSF abstract:</p>
<p>This study focuses on chemical processes that occur in oxygen-limited waters along the world's continental margins. These processes are influenced by the activities of microbes and control the fate of key elements that are deposited to sediments in these areas including carbon, nitrogen and sulfur. As a result, they are key to the health and function of the ocean. The intellectual merit of this research is to study the coupled chemical and microbial processes that occur in these environments by combining robotic technology with experiments that will be conducted at the ocean floor and in the shipboard laboratory. The broader impacts of this project will provide at-sea training and educational opportunities to undergraduate and graduate students and the results will be broadly distributed to stakeholders and interested parties. Results from this research promise to identify and quantify rates for key processes that couple carbon, nitrogen and sulfur in marine environments adjacent to the continents. The project addresses an important aspect of environmental change in the ocean (i.e., decreased oxygen due to warming and nutrient enrichment) and its influence on chemical and biological cycles and ocean ecosystems.</p>
<p>The dynamics of oxygen minimum zones along continental margins, and their potential for future expansion, are important because of their intersection with global biogeochemical cycles and because of their far-reaching impacts on ocean ecosystems. However, the impacts of transient deoxygenation on biogeochemical cycles of carbon, nitrogen and sulfur at the sea floor are not well established and are the focus of this study. This study will test the overarching hypothesis that deoxygenation triggers a positive feedback loop between bacterial mats at the sea floor that consume hydrogen sulfide, a sulfur species that can be toxic to higher organisms, and an underlying community of bacteria that produce hydrogen sulfide. By this hypothesis, the establishment of sea floor mats, which depend on inorganic nitrogen sources to run their sulfur metabolism, accelerates nitrogen cycling in the uppermost sediment horizon following deoxygenation. The accelerated nitrogen cycling allows for upward expansion of the sulfide-producing bacteria, which in-turn provide a shallow source of sulfide as substrate to further support nitrogen cycling in the sea floor mat. The results of this study will enable understanding of the relationship between oxygen dynamics in the water column and the biogeochemical processes at the sea floor that link the transformations of carbon, nitrogen and sulfur. The results of this study promise to define the environmental conditions under which the sulfur and nitrogen cycles are coupled and subject to strong positive feedbacks at the seafloor, as well as the conditions under which they are decoupled. This study provides training in research and innovative analytical and experimental techniques to four graduate students and several undergraduates. Undergraduates will be engaged in research at two institutions, one of which has recently been designated as a Hispanic serving institution. Approximately 10 undergraduate students (20 in total) will participate in each of the two proposed oceanographic expeditions, through an established course entitled: Field Studies in Marine Biogeochemistry. This course provides an opportunity for students to develop an independent research project in advance of the expedition, to participate on the expedition, and to conduct research projects while at sea.</p>
<p>This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.</p>
BASIN
largerWorkCitation
project
eng; USA
oceans
Santa Barbara Basin, California, northeast Pacific Ocean
-120.1164661
-120.0147509
34.14209313
34.36270433
2019-10-31
2019-11-09
Santa Barbara Basin, California, USA
0
BCO-DMO catalogue of parameters from Porewater geochemistry of sediments collected Fall 2019 in the Santa Barbara Basin using ROV Jason during R/V Atlantis cruise AT42-19
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
pointOfContact
http://lod.bco-dmo.org/id/dataset-parameter/867149.rdf
Name: Cruise
Units: unitless
Description: Cruise ID
http://lod.bco-dmo.org/id/dataset-parameter/867150.rdf
Name: Location
Units: unitless
Description: Sampling and cruise location
http://lod.bco-dmo.org/id/dataset-parameter/867151.rdf
Name: Latitude
Units: decimal degrees
Description: Latitude of sample collection
http://lod.bco-dmo.org/id/dataset-parameter/867152.rdf
Name: Longitude
Units: decimal degrees
Description: Longitude of sample collection; west is negative
http://lod.bco-dmo.org/id/dataset-parameter/867153.rdf
Name: ISO_DateTime_UTC
Units: unitless
Description: Date and time in ISO8601 standard format (YYYY-MM-DDThh:mm:ssZ)
http://lod.bco-dmo.org/id/dataset-parameter/867154.rdf
Name: Station
Units: unitless
Description: Station
http://lod.bco-dmo.org/id/dataset-parameter/867155.rdf
Name: Water_Depth
Units: meters (m)
Description: Water depth at sampling location
http://lod.bco-dmo.org/id/dataset-parameter/867156.rdf
Name: Sampling_Instrument
Units: unitless
Description: Sampling instrument used to obtain sediments
http://lod.bco-dmo.org/id/dataset-parameter/867157.rdf
Name: Sediment_Depth
Units: centimeters (cm)
Description: Depth of sediment core
http://lod.bco-dmo.org/id/dataset-parameter/867158.rdf
Name: Total_Alkalinity
Units: millimole per liter (mmol/L)
Description: Total alkalinity concentration in porewater
http://lod.bco-dmo.org/id/dataset-parameter/867159.rdf
Name: DIC
Units: millimole per liter (mmol/L)
Description: Dissolved inorganic carbon concentration in porewater
http://lod.bco-dmo.org/id/dataset-parameter/867160.rdf
Name: Iron_II
Units: micromole per liter (µmol/L)
Description: Iron (II) concentration in porewater
http://lod.bco-dmo.org/id/dataset-parameter/867161.rdf
Name: Total_Sulfide
Units: micromole per liter (µmol/L)
Description: Total sulfide concentration in porewater
http://lod.bco-dmo.org/id/dataset-parameter/867162.rdf
Name: Sulfate
Units: millimole per liter (mmol/L)
Description: Sulfate concentration in porewater
http://lod.bco-dmo.org/id/dataset-parameter/867163.rdf
Name: Ammonium
Units: micromole per liter (µmol/L)
Description: Ammonium ion concentration in porewater
http://lod.bco-dmo.org/id/dataset-parameter/867164.rdf
Name: Nitrate
Units: micromole per liter (µmol/L)
Description: Nitrate concentration in porewater
http://lod.bco-dmo.org/id/dataset-parameter/867165.rdf
Name: Nitrite
Units: micromole per liter (µmol/L)
Description: Nitrite concentration in porewater
http://lod.bco-dmo.org/id/dataset-parameter/867166.rdf
Name: Phosphate
Units: micromole per liter (µmol/L)
Description: Phosphate concentration in porewater
GB/NERC/BODC > British Oceanographic Data Centre, Natural Environment Research Council, United Kingdom
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
pointOfContact
https://www.bco-dmo.org/dataset/867007/data/download
download
onLine
dataset
<p>Sediments were collected with push cores (6 cm inner diameter) along three depth transects across the Santa Barbara Basin using the ROV Jason.&nbsp; Porewater was separated from sediment by centrifugation (4300 x g for 20 mins) in anoxic centrifugation vials and subsampled for further analysis.&nbsp;</p>
<p>Porewater geochemical properties were determined as listed:</p>
<ul>
<li>Porewater sulfate concentrations were determined by ion chromatography (Metrohm 761).</li>
<li>Porewater sulfide concentrations were determined spectrophotometrically (Shimadzu UV-Spectrophotometer UV-1800) according to Cline (1969).</li>
<li>Porewater ammonium, iron (II), and phosphate concentrations were determined spectrophotometrically (Shimadzu UV-Spectrophotometer UV-1800) according to Grasshoff et al. (1999).</li>
<li>Porewater nitrate and nitrite concentrations were determined spectrophotometrically (Shimadzu UV-Spectrophotometer UV-1800) according to García-Robledo et al. (2014).</li>
<li>Porewater Total Alkalinity was determined by titration according to Dale et al. 2015. Porewater Dissolved Inorganic Carbon was determined using a flow injection system (Hall &amp; Aller 1992).</li>
</ul>
<p>Note:&nbsp; Negative depths refer to measurements in the sediment core supernatant water.&nbsp; Supernatant water was collected with an anoxic syringe prior to core slicing.&nbsp;</p>
Specified by the Principal Investigator(s)
<p><strong>BCO-DMO Data Processing</strong><br />
- Imported data from source file "Treude_Valentine_BASIN_2019_datasets_BCO-DMO.xlsx" into the BCO-DMO processing tool<br />
- Combined data from multiple stations&nbsp;into a single file<br />
- Separated data for porewater, microbial, and sediment into individual tables<br />
- Modified parameter (column) names to conform with BCO-DMO naming conventions<br />
&nbsp; &nbsp; &nbsp;&nbsp;<em>The only allowed characters are A-Z,a-z,0-9, and underscores<br />
&nbsp; &nbsp; &nbsp; &nbsp;No spaces, hyphens, commas, parentheses, or Greek letters</em><br />
-&nbsp; Added column for Cruise<br />
-&nbsp;Changed date format from m/d/yyyy to yyyy-mm-dd (ISO Date 8601 format)<br />
-&nbsp;Added conventional header with dataset name, PI name, version date</p>
Specified by the Principal Investigator(s)
asNeeded
7.x-1.1
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
pointOfContact
Gravity Core
Gravity Core
PI Supplied Instrument Name: Gravity Core Instrument Name: Gravity Corer Instrument Short Name:Gravity Corer Instrument Description: The gravity corer allows researchers to sample sediment layers at the bottom of lakes or oceans. The coring device is deployed from the ship and gravity carries it to the seafloor. (http://www.whoi.edu/instruments/viewInstrument.do?id=1079). Community Standard Description: http://vocab.nerc.ac.uk/collection/L05/current/51/
Shimadzu UV-Spectrophotometer UV-1800
Shimadzu UV-Spectrophotometer UV-1800
PI Supplied Instrument Name: Shimadzu UV-Spectrophotometer UV-1800 PI Supplied Instrument Description:Shimadzu UV-Spectrophotometer UV-1800 was used to determine porewater sulfide, ammonum, iron(II), phosphate, nitrate, and nitrite concentrations Instrument Name: UV Spectrophotometer-Shimadzu Instrument Short Name:UV Spectrophotometer-Shimadzu Instrument Description: The Shimadzu UV Spectrophotometer is manufactured by Shimadzu Scientific Instruments (ssi.shimadzu.com). Shimadzu manufacturers several models of spectrophotometer; refer to dataset for make/model information. Community Standard Description: http://vocab.nerc.ac.uk/collection/L05/current/LAB20/
ROV Jason
ROV Jason
PI Supplied Instrument Name: ROV Jason PI Supplied Instrument Description:Sediments were collected with push cores in the Santa Barbara Basin using the ROV Jason. Instrument Name: ROV Jason Instrument Short Name:ROV Jason Instrument Description: The Remotely Operated Vehicle (ROV) Jason is operated by the Deep Submergence Laboratory (DSL) at Woods Hole Oceanographic Institution (WHOI). WHOI engineers and scientists designed and built the ROV Jason to give scientists access to the seafloor that didn't require them leaving the deck of the ship. Jason is a two-body ROV system. A 10-kilometer (6-mile) fiber-optic cable delivers electrical power and commands from the ship through Medea and down to Jason, which then returns data and live video imagery. Medea serves as a shock absorber, buffering Jason from the movements of the ship, while providing lighting and a bird’s eye view of the ROV during seafloor operations. During each dive (deployment of the ROV), Jason pilots and scientists work from a control room on the ship to monitor Jason’s instruments and video while maneuvering the vehicle and optionally performing a variety of sampling activities. Jason is equipped with sonar imagers, water samplers, video and still cameras, and lighting gear. Jason’s manipulator arms collect samples of rock, sediment, or marine life and place them in the vehicle’s basket or on "elevator" platforms that float heavier loads to the surface. More information is available from the operator site at URL.
flow injection system
flow injection system
PI Supplied Instrument Name: flow injection system PI Supplied Instrument Description:Porewater Dissolved Inorganic Carbon was determined using a flow injection system (Hall & Aller 1992). Instrument Name: Flow Injection Analyzer Instrument Short Name:FIA Instrument Description: An instrument that performs flow injection analysis. Flow injection analysis (FIA) is an approach to chemical analysis that is accomplished by injecting a plug of sample into a flowing carrier stream. FIA is an automated method in which a sample is injected into a continuous flow of a carrier solution that mixes with other continuously flowing solutions before reaching a detector. Precision is dramatically increased when FIA is used instead of manual injections and as a result very specific FIA systems have been developed for a wide array of analytical techniques. Community Standard Description: http://vocab.nerc.ac.uk/collection/L05/current/LAB36/
Metrohm 761
Metrohm 761
PI Supplied Instrument Name: Metrohm 761 PI Supplied Instrument Description:Porewater sulfate concentrations were determined by ion chromatography (Metrohm 761). Instrument Name: Ion Chromatograph Instrument Short Name:Ion Chromatograph Instrument Description: Ion chromatography is a form of liquid chromatography that measures concentrations of ionic species by separating them based on their interaction with a resin. Ionic species separate differently depending on species type and size. Ion chromatographs are able to measure concentrations of major anions, such as fluoride, chloride, nitrate, nitrite, and sulfate, as well as major cations such as lithium, sodium, ammonium, potassium, calcium, and magnesium in the parts-per-billion (ppb) range. (from http://serc.carleton.edu/microbelife/research_methods/biogeochemical/ic.html)
ROV push cores
ROV push cores
PI Supplied Instrument Name: ROV push cores PI Supplied Instrument Description:Sediments were collected with push cores (6 cm i.d.) along three depth transects across the Santa Barbara Basin using the ROV Jason. Instrument Name: Push Corer Instrument Short Name: Instrument Description: Capable of being performed in numerous environments, push coring is just as it sounds. Push coring is simply pushing the core barrel (often an aluminum or polycarbonate tube) into the sediment by hand. A push core is useful in that it causes very little disturbance to the more delicate upper layers of a sub-aqueous sediment.
Description obtained from: http://web.whoi.edu/coastal-group/about/how-we-work/field-methods/coring/
centrifuge
centrifuge
PI Supplied Instrument Name: centrifuge PI Supplied Instrument Description:Porewater was separated from sediment by centrifugation (4300 x g for 20 mins) in anoxic centrifugation vials and subsampled for further analysis. Instrument Name: Centrifuge Instrument Short Name: Instrument Description: A machine with a rapidly rotating container that applies centrifugal force to its contents, typically to separate fluids of different densities (e.g., cream from milk) or liquids from solids.
Cruise: AT42-19
AT42-19
R/V Atlantis
Community Standard Description
International Council for the Exploration of the Sea
R/V Atlantis
vessel
AT42-19
David L. Valentine
University of California-Santa Barbara
R/V Atlantis
Community Standard Description
International Council for the Exploration of the Sea
R/V Atlantis
vessel