year sample_id sml_uwc sample_type replicate date_time_UTC latitude longitude Al Ti V Mn Fe Ni Cu Zn Pb 2014 140725_UWC_FB_D uwc dissolved A 2014-07-25T20:30:00 24.825832 -80.814262 0.676 nd nd 0.777 0.448 0.130 0.107 0.220 0.009 2014 140725_SML_FB_1_D sml dissolved A 2014-07-25T20:30:00 24.825832 -80.814262 0.488 nd nd 0.798 0.297 0.131 0.101 BDL 0.008 2014 140725_SML_FB_2_D sml dissolved B 2014-07-25T20:30:00 24.825832 -80.814262 0.358 nd nd 0.848 0.243 0.127 0.099 BDL 0.007 2014 140726_UWC_FB_D uwc dissolved A 2014-07-26T13:00:00 24.825832 -80.814262 0.894 nd nd 0.626 0.494 0.133 0.089 0.237 0.009 2014 140726_SML_FB_1_D sml dissolved A 2014-07-26T13:00:00 24.825832 -80.814262 0.458 nd nd 0.595 0.290 0.133 0.094 0.237 0.008 2014 140726_SML_FB_2_D sml dissolved B 2014-07-26T13:00:00 24.825832 -80.814262 1.216 nd nd 0.667 1.017 0.130 0.093 BDL 0.011 2014 140728_UWC_FB_D uwc dissolved A 2014-07-28T00:00:00 24.825832 -80.814262 0.695 nd nd 0.134 0.197 0.132 0.105 BDL 0.002 2014 140728_SML_FB_D sml dissolved A 2014-07-28T00:00:00 24.825832 -80.814262 0.414 nd nd 0.148 0.190 0.131 0.110 0.217 0.002 2014 140728_UWC_AO_D uwc dissolved A 2014-07-28T14:00:00 24.740892 -80.981041 0.766 nd nd 0.339 0.229 0.113 0.122 BDL 0.005 2014 140728_SML_AO_1_D sml dissolved A 2014-07-28T14:00:00 24.740892 -80.981041 0.441 nd nd 0.341 0.232 0.117 0.118 0.228 0.005 2014 140728_SML_AO_2_D sml dissolved B 2014-07-28T14:00:00 24.740892 -80.981041 0.508 nd nd 0.401 0.186 0.118 0.120 0.294 0.006 2014 140728_SML_AO_3_D sml dissolved C 2014-07-28T14:00:00 24.740892 -80.981041 0.508 nd nd 0.397 0.145 0.117 0.114 BDL 0.004 2014 140725_UWC_FB_L uwc reactive_particulate A 2014-07-25T20:30:00 24.825832 -80.814262 0.255 BDL 0.013 0.111 0.920 0.004 0.005 0.097 0.004 2014 140725_SML_FB_1_L sml reactive_particulate A 2014-07-25T20:30:00 24.825832 -80.814262 0.594 BDL 0.023 0.220 2.166 0.006 0.005 0.074 0.011 2014 140725_SML_FB_2_L sml reactive_particulate B 2014-07-25T20:30:00 24.825832 -80.814262 0.262 BDL 0.008 0.126 1.086 0.006 0.002 0.052 0.006 2014 140726_UWC_FB_L uwc reactive_particulate A 2014-07-26T13:00:00 24.825832 -80.814262 1.272 0.001 0.030 0.517 3.094 0.017 0.012 0.180 0.021 2014 140726_SML_FB_1_L sml reactive_particulate A 2014-07-26T13:00:00 24.825832 -80.814262 1.459 BDL 0.024 0.566 3.701 0.012 0.007 0.113 0.026 2014 140726_SML_FB_2_L sml reactive_particulate B 2014-07-26T13:00:00 24.825832 -80.814262 1.413 0.003 0.026 0.517 3.544 0.012 0.008 0.093 0.026 2014 140728_UWC_FB_L uwc reactive_particulate A 2014-07-28T00:00:00 24.825832 -80.814262 0.210 BDL 0.007 1.025 1.348 0.008 0.004 0.088 0.013 2014 140728_SML_FB_L sml reactive_particulate A 2014-07-28T00:00:00 24.825832 -80.814262 0.217 BDL 0.007 0.852 1.261 0.003 0.004 0.094 0.013 2014 140728_UWC_AO_L uwc reactive_particulate A 2014-07-28T14:00:00 24.740892 -80.981041 0.183 BDL 0.024 0.072 0.385 0.005 0.005 0.056 0.002 2014 140728_SML_AO_1_L sml reactive_particulate A 2014-07-28T14:00:00 24.740892 -80.981041 0.097 BDL 0.002 0.056 0.310 0.002 0.006 0.080 0.004 2014 140728_SML_AO_2_L sml reactive_particulate B 2014-07-28T14:00:00 24.740892 -80.981041 0.077 BDL 0.006 0.063 0.333 0.003 0.005 0.061 0.002 2014 140728_SML_AO_3_L sml reactive_particulate C 2014-07-28T14:00:00 24.740892 -80.981041 0.225 BDL 0.011 0.075 0.526 0.005 0.005 0.032 0.002 2014 140725_UWC_FB_R uwc refractory_particulate A 2014-07-25T20:30:00 24.825832 -80.814262 8.167 0.747 0.016 0.022 3.331 0.066 0.006 0.037 0.009 2014 140725_SML_FB_1_R sml refractory_particulate A 2014-07-25T20:30:00 24.825832 -80.814262 22.73 1.774 0.043 0.047 9.425 0.017 0.008 0.023 0.004 2014 140725_SML_FB_2_R sml refractory_particulate B 2014-07-25T20:30:00 24.825832 -80.814262 10.31 0.802 0.019 0.023 4.247 0.003 0.004 0.010 0.002 2014 140726_UWC_FB_R uwc refractory_particulate A 2014-07-26T13:00:00 24.825832 -80.814262 35.43 2.839 0.060 0.080 14.04 0.026 0.016 0.044 0.006 2014 140726_SML_FB_1_R sml refractory_particulate A 2014-07-26T13:00:00 24.825832 -80.814262 46.11 3.013 0.084 0.091 18.70 0.058 0.019 0.040 0.008 2014 140726_SML_FB_2_R sml refractory_particulate B 2014-07-26T13:00:00 24.825832 -80.814262 46.33 3.068 0.080 0.102 18.92 0.030 0.028 0.056 0.010 2014 140728_UWC_FB_R uwc refractory_particulate A 2014-07-28T00:00:00 24.825832 -80.814262 6.503 1.528 0.013 0.073 2.695 0.012 0.003 0.010 0.002 2014 140728_SML_FB_R sml refractory_particulate A 2014-07-28T00:00:00 24.825832 -80.814262 6.525 0.612 0.013 0.057 2.880 0.004 0.005 0.011 0.002 2014 140728_UWC_AO_R uwc refractory_particulate A 2014-07-28T14:00:00 24.740892 -80.981041 0.939 0.349 0.002 0.006 0.810 0.002 0.003 0.006 0.000 2014 140728_SML_AO_1_R sml refractory_particulate A 2014-07-28T14:00:00 24.740892 -80.981041 0.901 0.629 0.004 0.010 0.568 0.033 0.002 0.005 0.000 2014 140728_SML_AO_2_R sml refractory_particulate B 2014-07-28T14:00:00 24.740892 -80.981041 1.839 0.425 0.016 0.009 0.804 0.023 0.004 0.009 0.000 2014 140728_SML_AO_3_R sml refractory_particulate C 2014-07-28T14:00:00 24.740892 -80.981041 6.724 0.620 0.013 0.022 3.065 0.010 0.012 0.127 0.018 2015 150505_UWC_SB_1_D uwc dissolved A 2015-05-05T12:00:00 24.661596 -81.454334 2.471 nd nd 0.857 1.188 0.120 0.176 2.120 0.006 2015 150505_UWC_SB_2_D uwc dissolved B 2015-05-05T12:00:00 24.661596 -81.454334 2.600 nd nd 0.750 1.076 0.122 0.178 3.210 0.006 2015 150505_UWC_SB_3_D uwc dissolved C 2015-05-05T12:00:00 24.661596 -81.454334 2.210 nd nd 0.720 1.111 0.124 0.163 1.706 0.007 2015 150505_SML_SB_1_D sml dissolved A 2015-05-05T12:00:00 24.661596 -81.454334 1.601 nd nd 1.025 0.897 0.122 0.175 5.752 0.008 2015 150505_SML_SB_2_D sml dissolved B 2015-05-05T12:00:00 24.661596 -81.454334 1.471 nd nd 0.700 0.868 0.121 0.159 5.468 0.008 2015 150505_SML_SB_3_D sml dissolved C 2015-05-05T12:00:00 24.661596 -81.454334 0.873 nd nd 0.711 0.882 0.120 0.129 0.477 0.008 2015 150506_UWC_LK_1_D uwc dissolved A 2015-05-06T13:00:00 24.550933 -81.417201 0.719 nd nd 0.191 0.143 0.116 0.084 BDL 0.003 2015 150506_UWC_LK_2_D uwc dissolved B 2015-05-06T13:00:00 24.550933 -81.417201 0.671 nd nd 0.182 0.109 0.115 0.086 0.213 0.003 2015 150506_SML_LK_1_D sml dissolved A 2015-05-06T13:00:00 24.550933 -81.417201 0.329 nd nd 0.201 0.057 0.115 0.088 1.484 0.004 2015 150506_SML_LK_2_D sml dissolved B 2015-05-06T13:00:00 24.550933 -81.417201 0.329 nd nd 0.196 0.045 0.116 0.083 2.256 0.004 2015 150506_UWC_SB_1_D uwc dissolved A 2015-05-06T20:00:00 24.661596 -81.454334 1.526 nd nd 0.437 0.770 0.128 0.116 BDL 0.007 2015 150506_UWC_SB_2_D uwc dissolved B 2015-05-06T20:00:00 24.661596 -81.454334 2.434 nd nd 0.549 0.679 0.121 0.133 1.606 0.006 2015 150506_UWC_SB_3_D uwc dissolved C 2015-05-06T20:00:00 24.661596 -81.454334 2.496 nd nd 0.521 0.760 0.118 0.130 1.467 0.006 2015 150506_SML_SB_1_D sml dissolved A 2015-05-06T20:00:00 24.661596 -81.454334 1.470 nd nd 0.560 0.580 0.117 0.132 4.116 0.007 2015 150506_SML_SB_2_D sml dissolved B 2015-05-06T20:00:00 24.661596 -81.454334 1.397 nd nd 0.551 0.556 0.118 0.133 3.112 0.007 2015 150506_SML_SB_3_D sml dissolved C 2015-05-06T20:00:00 24.661596 -81.454334 1.544 nd nd 0.593 0.593 0.119 0.128 3.622 0.007 2015 150507_UWC_SB_D uwc dissolved A 2015-05-07T19:00:00 24.661596 -81.454334 2.549 nd nd 0.673 0.860 0.122 0.146 3.145 0.006 2015 150507_SML_SB_D sml dissolved A 2015-05-07T19:00:00 24.661596 -81.454334 1.526 nd nd 0.686 0.692 0.145 0.140 4.848 0.006 2015 150508_UWC_SB_D uwc dissolved A 2015-05-08T20:00:00 24.661596 -81.454334 3.015 nd nd 0.823 0.836 0.122 0.138 1.588 0.009 2015 150508_SML_SB_D sml dissolved A 2015-05-08T20:00:00 24.661596 -81.454334 1.508 nd nd 0.714 0.616 0.127 0.137 11.58 0.009 2015 150509_UWC_LK_1_D uwc dissolved A 2015-05-09T12:00:00 24.550933 -81.417201 0.743 nd nd 0.216 0.112 0.118 0.080 0.411 0.003 2015 150509_UWC_LK_2_D uwc dissolved B 2015-05-09T12:00:00 24.550933 -81.417201 0.759 nd nd 0.243 0.066 0.112 0.077 0.212 0.003 2015 150509_SML_LK_1_D sml dissolved A 2015-05-09T12:00:00 24.550933 -81.417201 0.500 nd nd 0.259 0.058 0.119 0.082 5.674 0.006 2015 150509_SML_LK_2_D sml dissolved B 2015-05-09T12:00:00 24.550933 -81.417201 0.463 nd nd 0.264 0.098 0.117 0.082 2.699 0.005 2015 150509_UWC_SB_D uwc dissolved A 2015-05-09T20:00:00 24.661596 -81.454334 3.027 nd nd 0.780 0.826 0.124 0.134 1.604 0.006 2015 150509_SML_SB_D sml dissolved A 2015-05-09T20:00:00 24.661596 -81.454334 1.781 nd nd 0.704 0.712 0.135 0.145 7.824 0.010 2015 150505_UWC_SB_1_L uwc reactive_particulate A 2015-05-05T12:00:00 24.661596 -81.454334 0.423 0.005 0.012 0.035 1.351 0.013 0.010 0.052 0.004 2015 150505_UWC_SB_2_L uwc reactive_particulate B 2015-05-05T12:00:00 24.661596 -81.454334 0.475 0.008 0.014 0.042 1.436 0.002 0.009 0.062 0.004 2015 150505_UWC_SB_3_L uwc reactive_particulate C 2015-05-05T12:00:00 24.661596 -81.454334 0.431 0.006 0.009 0.044 1.402 0.003 0.008 0.125 0.004 2015 150505_SML_SB_1_L sml reactive_particulate A 2015-05-05T12:00:00 24.661596 -81.454334 0.350 0.006 0.007 0.028 1.127 0.068 0.009 0.101 0.003 2015 150505_SML_SB_2_L sml reactive_particulate B 2015-05-05T12:00:00 24.661596 -81.454334 0.472 0.005 0.009 0.028 1.069 0.001 0.007 0.084 0.003 2015 150505_SML_SB_3_L sml reactive_particulate C 2015-05-05T12:00:00 24.661596 -81.454334 0.301 0.006 0.009 0.030 1.003 0.001 0.006 0.052 0.003 2015 150506_UWC_LK_1_L uwc reactive_particulate A 2015-05-06T13:00:00 24.550933 -81.417201 0.104 BDL 0.029 0.028 0.101 0.002 0.008 0.031 0.002 2015 150506_UWC_LK_2_L uwc reactive_particulate B 2015-05-06T13:00:00 24.550933 -81.417201 0.105 BDL 0.029 0.029 0.096 0.001 0.003 0.038 0.001 2015 150506_SML_LK_1_L sml reactive_particulate A 2015-05-06T13:00:00 24.550933 -81.417201 0.049 BDL 0.006 0.022 0.050 0.001 0.003 0.027 0.000 2015 150506_SML_LK_2_L sml reactive_particulate B 2015-05-06T13:00:00 24.550933 -81.417201 0.102 BDL 0.006 0.021 0.048 0.001 0.002 0.020 0.000 2015 150506_UWC_SB_1_L uwc reactive_particulate A 2015-05-06T20:00:00 24.661596 -81.454334 0.445 0.011 0.010 0.032 1.425 0.002 0.006 0.033 0.006 2015 150506_UWC_SB_2_L uwc reactive_particulate B 2015-05-06T20:00:00 24.661596 -81.454334 0.242 0.015 0.015 0.042 1.282 0.017 0.010 0.042 0.007 2015 150506_UWC_SB_3_L uwc reactive_particulate C 2015-05-06T20:00:00 24.661596 -81.454334 0.227 0.009 0.009 0.025 1.271 0.001 0.004 0.010 0.005 2015 150506_SML_SB_1_L sml reactive_particulate A 2015-05-06T20:00:00 24.661596 -81.454334 0.310 0.007 0.005 0.017 0.869 0.001 0.003 0.008 0.003 2015 150506_SML_SB_2_L sml reactive_particulate B 2015-05-06T20:00:00 24.661596 -81.454334 0.116 0.008 BDL 0.013 0.697 0.000 0.003 0.012 0.007 2015 150506_SML_SB_3_L sml reactive_particulate C 2015-05-06T20:00:00 24.661596 -81.454334 0.128 0.006 BDL 0.014 0.742 0.001 0.002 0.013 0.002 2015 150507_UWC_SB_L uwc reactive_particulate A 2015-05-07T19:00:00 24.661596 -81.454334 0.219 0.004 0.010 0.027 1.718 0.001 0.004 0.016 0.006 2015 150507_SML_SB_L sml reactive_particulate A 2015-05-07T19:00:00 24.661596 -81.454334 0.207 BDL 0.006 0.047 1.556 0.001 0.005 0.046 0.004 2015 150508_UWC_SB_L uwc reactive_particulate A 2015-05-08T20:00:00 24.661596 -81.454334 0.210 0.004 0.007 0.022 1.568 0.002 0.005 0.053 BDL 2015 150508_SML_SB_L sml reactive_particulate A 2015-05-08T20:00:00 24.661596 -81.454334 0.207 0.005 0.005 0.016 1.177 0.000 0.009 0.030 0.011 2015 150509_UWC_LK_1_L uwc reactive_particulate A 2015-05-09T12:00:00 24.550933 -81.417201 0.160 BDL BDL 0.012 0.068 0.002 0.003 0.009 0.001 2015 150509_UWC_LK_2_L uwc reactive_particulate B 2015-05-09T12:00:00 24.550933 -81.417201 0.071 BDL BDL 0.010 0.055 0.001 0.002 0.007 0.000 2015 150509_SML_LK_1_L sml reactive_particulate A 2015-05-09T12:00:00 24.550933 -81.417201 0.053 BDL BDL 0.012 0.079 0.001 0.003 0.016 0.001 2015 150509_SML_LK_2_L sml reactive_particulate B 2015-05-09T12:00:00 24.550933 -81.417201 0.055 BDL BDL 0.010 0.063 0.001 0.002 0.017 0.000 2015 150509_UWC_SB_L uwc reactive_particulate A 2015-05-09T20:00:00 24.661596 -81.454334 0.235 0.005 0.008 0.025 1.931 0.002 0.004 0.027 0.006 2015 150509_SML_SB_L sml reactive_particulate A 2015-05-09T20:00:00 24.661596 -81.454334 0.212 0.006 0.006 0.019 1.607 0.001 0.003 0.025 0.005 2015 150505_UWC_SB_1_R uwc refractory_particulate A 2015-05-05T12:00:00 24.661596 -81.454334 5.417 0.476 0.007 0.008 1.460 0.077 0.008 0.015 0.002 2015 150505_UWC_SB_2_R uwc refractory_particulate B 2015-05-05T12:00:00 24.661596 -81.454334 10.92 2.555 0.011 0.013 1.897 0.110 0.010 0.098 0.007 2015 150505_UWC_SB_3_R uwc refractory_particulate C 2015-05-05T12:00:00 24.661596 -81.454334 5.843 0.202 0.013 0.007 1.479 0.043 0.007 0.030 0.002 2015 150505_SML_SB_1_R sml refractory_particulate A 2015-05-05T12:00:00 24.661596 -81.454334 4.729 0.175 0.008 0.005 1.223 BDL 0.005 0.022 0.002 2015 150505_SML_SB_2_R sml refractory_particulate B 2015-05-05T12:00:00 24.661596 -81.454334 3.736 0.025 0.006 0.004 0.871 0.058 0.005 0.065 0.002 2015 150505_SML_SB_3_R sml refractory_particulate C 2015-05-05T12:00:00 24.661596 -81.454334 4.568 0.223 0.006 0.009 1.270 0.054 0.008 0.056 0.002 2015 150506_UWC_LK_1_R uwc refractory_particulate A 2015-05-06T13:00:00 24.550933 -81.417201 1.141 0.009 0.007 0.003 0.332 0.002 0.005 0.005 0.000 2015 150506_UWC_LK_2_R uwc refractory_particulate B 2015-05-06T13:00:00 24.550933 -81.417201 1.547 0.175 0.004 0.004 0.309 0.008 0.004 0.063 0.001 2015 150506_SML_LK_1_R sml refractory_particulate A 2015-05-06T13:00:00 24.550933 -81.417201 0.838 0.184 0.002 0.002 0.132 0.008 0.002 0.016 0.001 2015 150506_SML_LK_2_R sml refractory_particulate B 2015-05-06T13:00:00 24.550933 -81.417201 0.608 0.037 BDL 0.004 0.137 0.031 0.004 0.012 0.001 2015 150506_UWC_SB_1_R uwc refractory_particulate A 2015-05-06T20:00:00 24.661596 -81.454334 8.681 1.986 0.010 0.017 2.887 0.039 0.008 0.051 0.003 2015 150506_UWC_SB_2_R uwc refractory_particulate B 2015-05-06T20:00:00 24.661596 -81.454334 6.827 1.073 0.010 0.013 2.733 0.010 0.010 0.033 0.001 2015 150506_UWC_SB_3_R uwc refractory_particulate C 2015-05-06T20:00:00 24.661596 -81.454334 5.275 0.917 0.007 0.011 1.927 0.013 0.006 0.018 0.001 2015 150506_SML_SB_1_R sml refractory_particulate A 2015-05-06T20:00:00 24.661596 -81.454334 4.046 0.864 0.005 0.002 1.297 BDL 0.004 BDL 0.000 2015 150506_SML_SB_2_R sml refractory_particulate B 2015-05-06T20:00:00 24.661596 -81.454334 3.102 0.859 0.005 0.007 1.073 BDL 0.003 0.007 0.001 2015 150506_SML_SB_3_R sml refractory_particulate C 2015-05-06T20:00:00 24.661596 -81.454334 3.236 0.884 0.004 0.007 1.032 BDL 0.003 0.038 0.001 2015 150507_UWC_SB_R uwc refractory_particulate A 2015-05-07T19:00:00 24.661596 -81.454334 5.222 0.741 0.007 0.006 1.949 BDL 0.004 0.002 0.001 2015 150507_SML_SB_R sml refractory_particulate A 2015-05-07T19:00:00 24.661596 -81.454334 4.359 1.130 0.006 0.014 1.564 0.003 0.005 0.042 0.001 2015 150508_UWC_SB_R uwc refractory_particulate A 2015-05-08T20:00:00 24.661596 -81.454334 4.119 0.721 0.006 0.005 1.687 BDL 0.004 0.025 0.112 2015 150508_SML_SB_R sml refractory_particulate A 2015-05-08T20:00:00 24.661596 -81.454334 2.944 0.689 0.004 BDL 1.220 0.006 0.004 0.034 0.000 2015 150509_UWC_LK_1_R uwc refractory_particulate A 2015-05-09T12:00:00 24.550933 -81.417201 1.127 0.526 BDL 0.002 0.171 0.020 0.003 0.001 0.001 2015 150509_UWC_LK_2_R uwc refractory_particulate B 2015-05-09T12:00:00 24.550933 -81.417201 0.865 0.124 0.003 BDL 0.105 BDL 0.003 0.387 0.001 2015 150509_SML_LK_1_R sml refractory_particulate A 2015-05-09T12:00:00 24.550933 -81.417201 0.935 0.311 BDL 0.003 0.394 0.001 0.004 0.001 0.001 2015 150509_SML_LK_2_R sml refractory_particulate B 2015-05-09T12:00:00 24.550933 -81.417201 0.591 0.197 BDL 0.004 0.262 0.015 0.002 0.005 0.000 2015 150509_UWC_SB_R uwc refractory_particulate A 2015-05-09T20:00:00 24.661596 -81.454334 5.564 1.160 0.007 0.006 2.181 0.017 0.004 0.004 0.002 2015 150509_SML_SB_R sml refractory_particulate A 2015-05-09T20:00:00 24.661596 -81.454334 6.471 1.713 0.007 0.010 1.905 0.007 0.005 0.029 0.004