http://lod.bco-dmo.org/id/dataset/3830
eng; USA
utf8
dataset
Highest level of data collection, from a common set of sensors or instrumentation, usually within the same research project
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
pointOfContact
2012-12-31
ISO 19115-2 Geographic Information - Metadata - Part 2: Extensions for Imagery and Gridded Data
ISO 19115-2:2009(E)
Surface transects for arsenic speciation, antimony speciation, and alkaline phosphatase activity from R/V Knorr cruise KN204-01 in the Subtropical North Atlantic Ocean in 2011 (U.S. GEOTRACES NAT project)
2013-01-03
publication
2013-01-03
revision
Marine Biological Laboratory/Woods Hole Oceanographic Institution Library (MBLWHOI DLA)
2020-04-10
publication
https://doi.org/10.26008/1912/bco-dmo.3830.1
Gregory Cutter
Old Dominion University
principalInvestigator
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
publisher
documentDigital
Cite this dataset as: Cutter, G. (2013) Surface transects for arsenic speciation, antimony speciation, and alkaline phosphatase activity from R/V Knorr cruise KN204-01 in the Subtropical North Atlantic Ocean in 2011 (U.S. GEOTRACES NAT project). Biological and Chemical Oceanography Data Management Office (BCO-DMO). Dataset version 2013-01-03 [if applicable, indicate subset used]. doi:10.26008/1912/bco-dmo.3830.1 [access date]
Surface transects for arsenic speciation, antimony speciation, and alkaline phosphatase activity Dataset Description: <p>Surface transects for arsenic speciation, antimony speciation, and alkaline phosphatase activity</p>
<p>Data for the concentrations of the dissolved (&lt;0.4 µm) arsenic species: total inorganic As (III+V), arsenite (AsIII), As(V), monomethyl As, dimethyl As,&nbsp; and the activity of the enzyme alkaline phosphatase (unfiltered).</p>
<p>Please note that some US GEOTRACES data may not be final, pending intercalibration results and further analysis. If you are interested in following changes to US GEOTRACES NAT data, there is an RSS feed available via the BCO-DMO <a href="http://www.bco-dmo.org/project/2066">US GEOTRACES project page</a> (http://www.bco-dmo.org/project/2066; scroll down and expand the "Datasets" section).</p> Acquisition Description: <p>Filtered (0.4 micromole) water samples from the Geotraces surface tow-fish taken at discrete times were placed into 500 mL Teflon FEP bottles, refrigerated, and analyzed within 24 hours of collection. Arsenic and antimony speciation determined using selective hydride generation, liquid nitrogen-cooled trapping, and then revolatilization and determination with gas chromatography/photoionization detection (Cutter et al., 1991; Cutter and Cutter, 2006).</p>
<p>Calibration performed daily via the standard additions method, with a minimum of 4 additions of AsIII, AsV, MMAs, or DMAs depending on the analyses. The slope from the linear fit to these data was then applied to all samples for that day. Detection limits were 25 pmol/L for As(III) and As(III+V), and 50 pmol/L for MMAs and DMAs. Precision was better than 8% (relative standard deviation) for all As species. Alkaline phosphatase enzyme activity was measured using the fluorescence method of Ammerman (1993).</p>
Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-0926423 Award URL: http://www.nsf.gov/awardsearch/showAward.do?AwardNumber=0926423
Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-0926092 Award URL: http://www.nsf.gov/awardsearch/showAward.do?AwardNumber=0926092
completed
Gregory Cutter
Old Dominion University
757-683-4929
Department of Ocean, Earth, and Atmospheric Sciences 4500 Elkhorn Ave
Norfolk
VA
23529-0276
USA
gcutter@odu.edu
pointOfContact
asNeeded
Dataset Version: 1
Unknown
cruise_id
geofish_station
date
time
lat
lon
AsIII
TAs
MMAs
DMAs
AP_Turnover_Time
AP_Turnover_Rate
As
cruise_part
GeoFish
towed undulating vehicle
Gas Chromatograph
theme
None, User defined
cruise id
geofish_station
date
time of day
latitude
longitude
no standard parameter
arsenic
cruise_part
featureType
BCO-DMO Standard Parameters
GeoFish Towed near-Surface Sampler
towed undulating vehicle
Gas Chromatograph
instrument
BCO-DMO Standard Instruments
KN204-01
service
Deployment Activity
Subtropical northern Atlantic Ocean
place
Locations
otherRestrictions
otherRestrictions
Access Constraints: none. Use Constraints: Please follow guidelines at: http://www.bco-dmo.org/terms-use Distribution liability: Under no circumstances shall BCO-DMO be liable for any direct, incidental, special, consequential, indirect, or punitive damages that result from the use of, or the inability to use, the materials in this data submission. If you are dissatisfied with any materials in this data submission your sole and exclusive remedy is to discontinue use.
U.S. GEOTRACES
http://www.geotraces.org/
U.S. GEOTRACES
GEOTRACES is a SCOR sponsored program; and funding for program infrastructure development is provided by the U.S. National Science Foundation.
GEOTRACES gained momentum following a special symposium, S02: Biogeochemical cycling of trace elements and isotopes in the ocean and applications to constrain contemporary marine processes (GEOSECS II), at a 2003 Goldschmidt meeting convened in Japan. The GEOSECS II acronym referred to the Geochemical Ocean Section Studies To determine full water column distributions of selected trace elements and isotopes, including their concentration, chemical speciation, and physical form, along a sufficient number of sections in each ocean basin to establish the principal relationships between these distributions and with more traditional hydrographic parameters;
* To evaluate the sources, sinks, and internal cycling of these species and thereby characterize more completely the physical, chemical and biological processes regulating their distributions, and the sensitivity of these processes to global change; and
* To understand the processes that control the concentrations of geochemical species used for proxies of the past environment, both in the water column and in the substrates that reflect the water column.
GEOTRACES will be global in scope, consisting of ocean sections complemented by regional process studies. Sections and process studies will combine fieldwork, laboratory experiments and modelling. Beyond realizing the scientific objectives identified above, a natural outcome of this work will be to build a community of marine scientists who understand the processes regulating trace element cycles sufficiently well to exploit this knowledge reliably in future interdisciplinary studies.
Expand "Projects" below for information about and data resulting from individual US GEOTRACES research projects.
U.S. GEOTRACES
largerWorkCitation
program
U.S. GEOTRACES North Atlantic Transect
http://www.geotraces.org/
U.S. GEOTRACES North Atlantic Transect
<p><em>Much of this text appeared in an article published in OCB News, October 2008, by the OCB Project Office.</em></p>
<p>The first U.S. GEOTRACES Atlantic Section will be specifically centered around a sampling cruise to be carried out in the North Atlantic in 2010. Ed Boyle (MIT) and Bill Jenkins (WHOI) organized a three-day planning workshop that was held September 22-24, 2008 at the Woods Hole Oceanographic Institution. The main goal of the workshop, sponsored by the National Science Foundation and the U.S. GEOTRACES Scientific Steering Committee, was to design the implementation plan for the first U.S. GEOTRACES Atlantic Section. The primary cruise design motivation was to improve knowledge of the sources, sinks and internal cycling of Trace Elements and their Isotopes (TEIs) by studying their distributions along a section in the North Atlantic (Figure 1). The North Atlantic has the full suite of processes that affect TEIs, including strong meridional advection, boundary scavenging and source effects, aeolian deposition, and the salty Mediterranean Outflow. The North Atlantic is particularly important as it lies at the "origin" of the global Meridional Overturning Circulation.</p>
<p>It is well understood that many trace metals play important roles in biogeochemical processes and the carbon cycle, yet very little is known about their large-scale distributions and the regional scale processes that affect them. Recent advances in sampling and analytical techniques, along with advances in our understanding of their roles in enzymatic and catalytic processes in the open ocean provide a natural opportunity to make substantial advances in our understanding of these important elements. Moreover, we are motivated by the prospect of global change and the need to understand the present and future workings of the ocean's biogeochemistry. The GEOTRACES strategy is to measure a broad suite of TEIs to constrain the critical biogeochemical processes that influence their distributions. In addition to these "exotic" substances, more traditional properties, including macronutrients (at micromolar and nanomolar levels), CTD, bio-optical parameters, and carbon system characteristics will be measured. The cruise starts at Line W, a repeat hydrographic section southeast of Cape Cod, extends to Bermuda and subsequently through the North Atlantic oligotrophic subtropical gyre, then transects into the African coast in the northern limb of the coastal upwelling region. From there, the cruise goes northward into the Mediterranean outflow. The station locations shown on the map are for the "fulldepth TEI" stations, and constitute approximately half of the stations to be ultimately occupied.</p>
<p><em>Figure 1. The proposed 2010 Atlantic GEOTRACES cruise track plotted on dissolved oxygen at 400 m depth. Data from the World Ocean Atlas (Levitus et al., 2005) were plotted using Ocean Data View (courtesy Reiner Schlitzer). [click on the image to view a larger version]</em><br /><a href="http://bcodata.whoi.edu/US_GEOTRACES/AtlanticSection/GEOTRACES_Atl_stas.jpg" target="_blank"><img alt="" src="https://datadocs.bco-dmo.org/d2/US_GEOTRACES/AtlanticSection/GEOTRACES_Atl_stas.jpg" style="width:350px" /></a></p>
<p>Hydrography, CTD and nutrient measurements will be supported by the Ocean Data Facility (J. Swift) at Scripps Institution of Oceanography and funded through NSF Facilities. They will be providing an additional CTD rosette system along with nephelometer and LADCP. A trace metal clean Go-Flo Rosette and winch will be provided by the group at Old Dominion University (G. Cutter) along with a towed underway pumping system.</p>
<p>The North Atlantic Transect cruise began in 2010 with KN199 leg 4 (station sampling) and leg 5 (underway sampling only) (Figure 2).</p>
<p><a href="http://bcodata.whoi.edu//US_GEOTRACES/AtlanticSection/Cruise_Report_for_Knorr_199_Final_v3.pdf" target="_blank">KN199-04 Cruise Report (PDF)</a></p>
<p><em>Figure 2. The red line shows the cruise track for the first leg of the US Geotraces North Atlantic Transect on the R/V Knorr in October 2010. The rest of the stations (beginning with 13) will be completed in October-December 2011 on the R/V Knorr (courtesy of Bill Jenkins, Chief Scientist, GNAT first leg). [click on the image to view a larger version]</em><br /><a href="http://bcodata.whoi.edu/US_GEOTRACES/AtlanticSection/GNAT_stationPlan.jpg" target="_blank"><img alt="Atlantic Transect Station location map" src="https://datadocs.bco-dmo.org/d2/US_GEOTRACES/AtlanticSection/GNAT_stationPlan_sm.jpg" style="width:350px" /></a></p>
<p>The section completion effort resumed again in November 2011 with KN204-01A,B (Figure 3).</p>
<p><a href="http://bcodata.whoi.edu//US_GEOTRACES/AtlanticSection/Submitted_Preliminary_Cruise_Report_for_Knorr_204-01.pdf" target="_blank">KN204-01A,B Cruise Report (PDF)</a></p>
<p><em>Figure 3. Station locations occupied on the US Geotraces North Atlantic Transect on the R/V Knorr in November 2011. [click on the image to view a larger version]</em><br /><a href="http://bcodata.whoi.edu/US_GEOTRACES/AtlanticSection/KN204-01_Stations.png" target="_blank"><img alt="Atlantic Transect/Part 2 Station location map" src="https://datadocs.bco-dmo.org/d2/US_GEOTRACES/AtlanticSection/KN204-01_Stations.png" style="width:350px" /></a></p>
<p>Data from the North Atlantic Transect cruises are available under the Datasets heading below, and consensus values for the SAFe and North Atlantic GEOTRACES Reference Seawater Samples are available from the GEOTRACES Program Office: <a href="http://www.geotraces.org/science/intercalibration/322-standards-and-reference-materials?acm=455_215" target="_blank">Standards and Reference Materials</a></p>
<p><strong>ADCP data</strong> are available from the Currents ADCP group at the University of Hawaii at the links below:<br /><a href="http://currents.soest.hawaii.edu/uhdas_adcp/year2010.html#kn199_4" target="_blank">KN199-04</a> (leg 1 of 2010 cruise; Lisbon to Cape Verde)<br /><a href="http://currents.soest.hawaii.edu/uhdas_adcp/year2010.html#kn199_5" target="_blank">KN199-05</a> (leg 2 of 2010 cruise; Cape Verde to Charleston, NC)<br /><a href="http://currents.soest.hawaii.edu/uhdas_adcp/year2011.html#kn204_01" target="_blank">KN204-01A</a> (part 1 of 2011 cruise; Woods Hole, MA to Bermuda)<br /><a href="http://currents.soest.hawaii.edu/uhdas_adcp/year2011.html#kn204_02" target="_blank">KN204-01B</a> (part 2 of 2011 cruise; Bermuda to Cape Verde)</p>
U.S. GEOTRACES NAT
largerWorkCitation
project
eng; USA
oceans
Subtropical northern Atlantic Ocean
-69.8106
-24.5337
17.417
38.6944
2011-11-08
2011-12-09
Subtropical western and eastern North Atlantic Ocean
0
BCO-DMO catalogue of parameters from Surface transects for arsenic speciation, antimony speciation, and alkaline phosphatase activity from R/V Knorr cruise KN204-01 in the Subtropical North Atlantic Ocean in 2011 (U.S. GEOTRACES NAT project)
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
pointOfContact
http://lod.bco-dmo.org/id/dataset-parameter/31493.rdf
Name: cruise_id
Units: text
Description: cruise id
http://lod.bco-dmo.org/id/dataset-parameter/31494.rdf
Name: geofish_station
Units: text
Description: towed fish station
http://lod.bco-dmo.org/id/dataset-parameter/31495.rdf
Name: date
Units: YYYYMMDD
Description: Date
http://lod.bco-dmo.org/id/dataset-parameter/31496.rdf
Name: time
Units: HHMM
Description: Time
http://lod.bco-dmo.org/id/dataset-parameter/31497.rdf
Name: lat
Units: decimal degrees
Description: Latitude (South is negative)
http://lod.bco-dmo.org/id/dataset-parameter/31498.rdf
Name: lon
Units: decimal degrees
Description: Longitude (West is negative)
http://lod.bco-dmo.org/id/dataset-parameter/31499.rdf
Name: AsIII
Units: nmol/L
Description: Arsenite (HAsO32-)
http://lod.bco-dmo.org/id/dataset-parameter/31500.rdf
Name: TAs
Units: nmol/L
Description: Total inorganic arsenic (AsIII+V)
http://lod.bco-dmo.org/id/dataset-parameter/31501.rdf
Name: MMAs
Units: nmol/L
Description: Monomethyl arsenic
http://lod.bco-dmo.org/id/dataset-parameter/31502.rdf
Name: DMAs
Units: nmol/L
Description: Dimethyl arsenic
http://lod.bco-dmo.org/id/dataset-parameter/31503.rdf
Name: AP_Turnover_Time
Units: hours
Description: Alkaline phosphatase turnover time
http://lod.bco-dmo.org/id/dataset-parameter/31504.rdf
Name: AP_Turnover_Rate
Units: h-1
Description: Alkaline phosphatase turnover rate
http://lod.bco-dmo.org/id/dataset-parameter/31505.rdf
Name: As
Units: nanomoles/liter
Description: Arsenic As(V)
http://lod.bco-dmo.org/id/dataset-parameter/31566.rdf
Name: cruise_part
Units: dimensionless
Description: Identifier for a segment of a leg of a cruise, where a leg may have been broken into parts.
GB/NERC/BODC > British Oceanographic Data Centre, Natural Environment Research Council, United Kingdom
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
pointOfContact
https://www.bco-dmo.org/dataset/3830/data/download
download
onLine
dataset
<p>Filtered (0.4 micromole) water samples from the Geotraces surface tow-fish taken at discrete times were placed into 500 mL Teflon FEP bottles, refrigerated, and analyzed within 24 hours of collection. Arsenic and antimony speciation determined using selective hydride generation, liquid nitrogen-cooled trapping, and then revolatilization and determination with gas chromatography/photoionization detection (Cutter et al., 1991; Cutter and Cutter, 2006).</p>
<p>Calibration performed daily via the standard additions method, with a minimum of 4 additions of AsIII, AsV, MMAs, or DMAs depending on the analyses. The slope from the linear fit to these data was then applied to all samples for that day. Detection limits were 25 pmol/L for As(III) and As(III+V), and 50 pmol/L for MMAs and DMAs. Precision was better than 8% (relative standard deviation) for all As species. Alkaline phosphatase enzyme activity was measured using the fluorescence method of Ammerman (1993).</p>
Specified by the Principal Investigator(s)
<p>Samples analyzed in duplicate or triplicate and means computed.</p>
Specified by the Principal Investigator(s)
asNeeded
7.x-1.1
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
pointOfContact
GeoFish
GeoFish
PI Supplied Instrument Name: GeoFish Instrument Name: GeoFish Towed near-Surface Sampler Instrument Short Name:GeoFish Instrument Description: The GeoFish towed sampler is a custom designed near surface ( Community Standard Description: http://vocab.nerc.ac.uk/collection/L05/current/31/
towed undulating vehicle
towed undulating vehicle
PI Supplied Instrument Name: towed undulating vehicle Instrument Name: towed undulating vehicle Instrument Short Name:TUV Instrument Description: A towed undulating vehicle is a generic class of instruments. See the data set specific information for a detailed description. These are often prototype instrument packages designed to make very specific measurements.
Gas Chromatograph
Gas Chromatograph
PI Supplied Instrument Name: Gas Chromatograph Instrument Name: Gas Chromatograph Instrument Short Name:Gas Chromatograph Instrument Description: Instrument separating gases, volatile substances, or substances dissolved in a volatile solvent by transporting an inert gas through a column packed with a sorbent to a detector for assay. (from SeaDataNet, BODC) Community Standard Description: http://vocab.nerc.ac.uk/collection/L05/current/LAB02/
Cruise: KN204-01
KN204-01
R/V Knorr
Community Standard Description
International Council for the Exploration of the Sea
R/V Knorr
vessel
KN204-01
Edward A. Boyle
Massachusetts Institute of Technology
http://bcodata.whoi.edu/US_GEOTRACES/AtlanticSection/STS_Prelim_GT11_Doc.pdf
Report describing KN204-01
R/V Knorr
Community Standard Description
International Council for the Exploration of the Sea
R/V Knorr
vessel