Chemical, isotopic, and temporal variations during crustal differentiation : insights from the Dariv Igneous Complex, Western Mongolia
Bucholz, Claire E.
MetadataShow full item record
LocationDariv Igneous Complex, Western Mongolia
Fractional crystallization of mantle-derived basaltic melts is a critical process in producing a compositionally stratified continental crust characterized by a silicic upper crust and a mafic lower crust. This thesis explores outstanding questions associated with fractional crystallization through detailed field, petrological, and geochemical studies of the Dariv Igneous Complex in Western Mongolia. The Dariv Igneous Complex records the crystallization of a high-K primitive arc melt at shallow crustal levels, preserving both biotite-bearing ultramafic and mafic cumulates, as well as liquid-like evolved plutonics, such as (quartz-)monzonites. Chapter 2 presents comprehensive field and petrographic descriptions of the complex and establishes the petrogenetic groundwork to understand the conditions under which it formed. Results of this study indicate that the observed lithologies formed through the fractional crystallization of a high-K hydrous basalt, typical of alkali-rich basalts found in subduction zone settings, at 0.2-0.5 GPa and elevated oxygen fugacities. Chapter 3 presents a quantitatively modeled liquid line of descent (LLD) for the complex based on whole rock geochemical analyses, which is able to explain the trends observed in the monzonitic plutonic series observed in continental arcs. The oxygen isotope trajectory of fractionally crystallizing melts is rigorously constrained through modeling and mineral analyses in Chapter 4. This study indicates that large (1 to 1.8‰) increases in δ18O as a melt evolves from basaltic to granitic in composition due to the fractionation of low δ18O minerals. As such, the majority of δ18O values of upper crustal silicic plutonics can be explained through fractional crystallization of primitive arc basalts alone without needing to invoke assimilation of high δ18O crustal material. Finally, Chapter 5 explores the timescales associated with fractional crystallization through high precision U-Pb geochronology of zircon from the Dariv Igneous Complex. Evolution from a basaltic melt to a silica-rich monzonitic melt in the Dariv Igneous Complex occurred in <300 ka. If rates of fractional crystallization are primarily a function of cooling, this study provides an end-member constraint for fractional crystallization of a basaltic melt at relatively cool, shallow crustal levels. Together, these studies advance our understanding of the compositional, isotopic, and temporal variations associated with the formation of the continental crust.
Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution February 2016
Showing items related by title, author, creator and subject.
Experimental and seismological constraints on the rheology, evolution, and alteration of the lithosphere at oceanic spreading centers deMartin, Brian J. (Massachusetts Institute of Technology and Woods Hole Oceanographic Institution, 2007-02)Oceanic spreading centers are sites of magmatic, tectonic, and hydrothermal processes. In this thesis I present experimental and seismological constraints on the evolution of these complex regions of focused crustal ...
Caron, David A. (Massachusetts Institute of Technology and Woods Hole Oceanographic Institution, 1984-06)The distribution and feeding behavior of bacterivorous micro flagellates (2-20 μm protozoa) and their ingestion by copepods were examined in an attempt to assess the importance of these protozoa as a trophic link ...
Henrichs, Susan M. (Massachusetts Institute of Technology and Woods Hole Oceanographic Institution, 1980-08)Dissolved free amino acids (DFAA) were measured in interstitial water samples squeezed from sediments collected in a variety of depositional environments. These sediments were further characterized by measurements of ...