Auxiliary material for paper 2009JC005267 Seasonal forcing of summer dissolved inorganic carbon and chlorophyll a on the Western Shelf of the Antarctic Peninsula Martin Montes-Hugo Coastal Ocean Observation Laboratory, Institute of Marine and Coastal Sciences, School of Environmental and Biological Sciences, Rutgers University–State University of New Jersey, New Brunswick, New Jersey, USA. Colm Sweeney Global Monitoring Division, Earth Systems Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, Colorado, USA. Scott C. Doney Department of Marine Chemistry and Geochemistry, Woods Hole Oceanographic Institution, Woods Hole, Massachusetts, USA. Hugh Ducklow Ecosystems Center, Marine Biological Laboratory, Woods Hole, Massachusetts, USA. Robert Frouin Scripps Institution of Oceanography, University of California, San Diego, California, USA. Douglas G. Martinson Lamont-Doherty Earth Observatory–Department of Earth and Environmental Sciences, Columbia University, Palisades, New York, USA. Sharon Stammerjohn Ocean Sciences, University of California, Santa Cruz, California, USA. Oscar Schofield Coastal Ocean Observation Laboratory, Institute of Marine and Coastal Sciences, School of Environmental and Biological Sciences, Rutgers University–State University of New Jersey, New Brunswick, New Jersey, USA. Montes-Hugo, M., C. Sweeney, S. C. Doney, H. Ducklow, R. Frouin, D. G. Martinson, S. Stammerjohn, and O. Schofield (2010), Seasonal forcing of summer dissolved inorganic carbon and chlorophyll a on the western shelf of the Antarctic Peninsula, J. Geophys. Res., 115, C03024, doi:10.1029/2009JC005267. Introduction This data set includes additional information related to uncertainty of satellite-derived sea ice concentration, analysis of phytoplankton pigments, validation of DIC-derived pCO2, and linkage between summer stratification and sea concentration during preceding winter. 1. 2009jc005267-txts01.pdf Variation of chlorophyll a concentrations due to accessory pigments and methodological differences. (a) Relationship between HPLC-derived chlorophyll b (Chl bHPLC) and chlorophyll a (Chl aHPLC) concentration per unit of volume (empty circles), model fitting (solid line), (b) Covariation between averaged surface samples (0-20 m depth) of Chl aHPLC and chlorophyll a concentration per unit of volume measured by fluorometry and using the acid-method (Chl aFluo) (empty circles), model fitting (solid line), 1:1 relationship (dash line). Comparison between direct and DIC-derived measurements of pCO2 (empty circles), model fitting (solid line). Relationship between upper mixed layer (UMLD) during January and sea ice area (SIA) during previous winter; (a) monthly UMLD (black rectangles), winter SIA anomaly (empty circles), vertical bars indicate one standard error, (b) negative exponential fitting of averaged UMLD during January as a function of winter SIA anomaly (solid line), observations (solid circles), between parentheses is one standard error. References Comiso, J. C., D. Cavalieri, C. Parkinson, and P. Gloersen (1997), Passive microwave algorithms for sea ice concentration—A comparison of two techniques, Rem. Sens. Environ., 60, 357– 384. Smith, R.C., K.S. Baker, and P. Dustan (1981), Fluorometric techniques for the measurement of oceanic chlorophyll in the support of remote sensing. Report SIO ref 81-17, May 1981, University of California, San Diego, Scripps Institution of Oceanography, Visibility Laboratory, La Jolla, California. Takahashi, T., S.C. Sutherland, R. Wanninkhof, C. Sweeney, R.A. Feely, D.W. Chipman, B. Hales, G. Friederich, F. Chavez, C. Sabine, A. Watson, D.C. E. Bakker, U. Schuster, N. Metzl, H. Y. Inoue, M. Ishii, T. Midorikawa, Y. Nojiri, A. Koertzinger, T. Steinhoff, M. Hoppema, J. Olafsson, T. S. Arnarson, B. Tilbrook, T. Johannessen, A. Olsen, R. Bellerby, C. S. Wong, B. Delille, N. R. Bates, and H. J. W. de Baar (2008), Climatological Mean and Decadal Change in Surface Ocean pCO2, and Net Sea-air CO2 Flux over the Global Oceans, Deep -Sea Research II (in press). Trees, C., D.K.Clark, R.R. Bidigare, M.E. Ondrusek, and J.L. Mueller (2000), Accessory pigments versus chlorophyll a concentrations within the euphotic zone: A ubiquitous relationship Limnol. Oceanogr., 45: 1130–1143.